Synthesis, characterization and luminescence properties of coordination compounds of raire earth with p-tert-butyl-calix[8] arene
文献类型：期刊论文
| 作者 | Yan, L; Zhao, YL; Zhao, FY; Wang, LX; Ye, JP |
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2006-05-01 |
| 卷号 | 26期号:5页码:928-932 |
| 关键词 | Terbium Complexes P-tert-butyl-calix[8] Arene Dimethyl Sulphoxide n N-dimethylformamide |
| ISSN号 | 1000-0593 |
| 英文摘要 | Fourteen solid coordination compounds of rare earth(Sm3+, Eu3+, Tb3+, and Dy3+ and Ln(3+) (La3+,Gd3+ and Y3+)-doped Tb3+ with p-tert-butyl-calix[8] arene (LH8) have been synthesized and characterized. Elemental analysis, rare erth complexometry, H-1 NMR spectra and TG-DTA have been studied. The results suggest that the complexes have the composition of [RF2 (LH2)(DMSO)(5)]DMSO, [RE2 (LH2) (DMF)(5)]2DMF, [LnTb(LH2) (DMSO)(5)]DMSO and [LnTb(LH2) (DMF)(5)] 2DMF respectively. Fluorescence spectrum suggests that the Tb" complexes have characteristic luminescence, and its fluorescence intensity is enhanced after doping with La3+, Gd3+ and Y3+. The influence of the doping ions and two neutral ligands (DMSO and DMF) has also been discussed. In addition, the fluorescence lifetime of some complexes has been investigated. |
| 语种 | 英语 |
| WOS记录号 | WOS:000238045800036 |
| 出版者 | BEIJING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59589]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, YL |
| 作者单位 | 1.Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China 2.Inner Mongolia Univ, Dept Fundamental, Hohhot 010019, Peoples R China 3.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Photochem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, L,Zhao, YL,Zhao, FY,et al. Synthesis, characterization and luminescence properties of coordination compounds of raire earth with p-tert-butyl-calix[8] arene[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2006,26(5):928-932. |
| APA | Yan, L,Zhao, YL,Zhao, FY,Wang, LX,&Ye, JP.(2006).Synthesis, characterization and luminescence properties of coordination compounds of raire earth with p-tert-butyl-calix[8] arene.SPECTROSCOPY AND SPECTRAL ANALYSIS,26(5),928-932. |
| MLA | Yan, L,et al."Synthesis, characterization and luminescence properties of coordination compounds of raire earth with p-tert-butyl-calix[8] arene".SPECTROSCOPY AND SPECTRAL ANALYSIS 26.5(2006):928-932. |
入库方式： OAI收割
来源：化学研究所
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