Synthesis of palladium complexes containing 2-methoxycarbonyl-6-iminopyridine ligand and their catalytic behaviors in reaction of ethylene and norbornene
文献类型：期刊论文
| 作者 | Zhang, Wenjuan; Sun, Wen-Hua ; Wu, Biao; Zhang, Shu; Ma, Hongwei; Li, Yan; Chen, Jiutong; Hao, Peng
|
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2006-11-01 |
| 卷号 | 691期号:22页码:4759-4767 |
| 关键词 | Iminopyridine Palladium Complexes Ethylene Norbornene Polymerization |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2006.07.026 |
| 英文摘要 | A series of palladium complexes (C1-C7) have been prepared by the reaction of PdCl2(CH3CN)(2) with 2-methoxycarbonyl-6-iminopyridines, L1-L7. The 2-methoxycarbonyl-6-iminopyridines and their complexes were fully characterized by FT-IR, NMR spectra and elemental analysis. Structures of C1, C2, C4, C5 and C6, C7 were determined by X-ray crystallography, and these complexes fold slightly distorted square planar structures around palladium coordinated with two nitrogen atoms and two chlorides. These palladium complexes exhibited moderate catalytic activities for ethylene dimerization and/or polymerization in the presence of methylaluminoxane, and showed remarkable catalytic activity for norbornene polymerization. The catalytic behaviors of these complexes were highly affected by both the ligand employed and reaction conditions. (c) 2006 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000241650500022 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59631]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 4.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Wenjuan,Sun, Wen-Hua,Wu, Biao,et al. Synthesis of palladium complexes containing 2-methoxycarbonyl-6-iminopyridine ligand and their catalytic behaviors in reaction of ethylene and norbornene[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2006,691(22):4759-4767. |
| APA | Zhang, Wenjuan.,Sun, Wen-Hua.,Wu, Biao.,Zhang, Shu.,Ma, Hongwei.,...&Hao, Peng.(2006).Synthesis of palladium complexes containing 2-methoxycarbonyl-6-iminopyridine ligand and their catalytic behaviors in reaction of ethylene and norbornene.JOURNAL OF ORGANOMETALLIC CHEMISTRY,691(22),4759-4767. |
| MLA | Zhang, Wenjuan,et al."Synthesis of palladium complexes containing 2-methoxycarbonyl-6-iminopyridine ligand and their catalytic behaviors in reaction of ethylene and norbornene".JOURNAL OF ORGANOMETALLIC CHEMISTRY 691.22(2006):4759-4767. |
入库方式： OAI收割
来源：化学研究所
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