Synthesis and charaterization of Ru complex with terpyridine on quartz substrates surface
文献类型：期刊论文
| 作者 | Zhao Jian-Ying; Ma Li; Jin Ri-Zhe; Gao Lian-Xun |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2006-12-10 |
| 卷号 | 27期号:12页码:2337-2339 |
| 关键词 | Self-assemble Pyridine Ru Complex Schiff Base |
| ISSN号 | 0251-0790 |
| 英文摘要 | The 6-carboxaldehyde-2, 2': 6', 2"-terpyridine was synthesized and assembled on the aminosilanization quartz substrate by the Schiff base interfacial group. Then the substrate was reacted with ruthenium and 6-bromo-2,2'-bipyridine to form a new Schiff base type Ru complexes. The process of the complexes assembled was characterized by UV-Vis absorption spectra and XPS. The film exhibited photoluminescence arising from pi* -t(2g) ligand-to-metal transition of Ru complex. From the fluorescent spectra, we observed the behavior of Ru (II) complexes is greatly affected by the schiff base ligand. The novel Schiff base ligand Ru (II) complexes exhibited strong and pure luminescent intensity. It was different from the other type ruthenium complexes. The result shows that there are many ralations between the structure and the properties of the complex. |
| 语种 | 英语 |
| WOS记录号 | WOS:000242962700023 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59679]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao Lian-Xun |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao Jian-Ying,Ma Li,Jin Ri-Zhe,et al. Synthesis and charaterization of Ru complex with terpyridine on quartz substrates surface[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2006,27(12):2337-2339. |
| APA | Zhao Jian-Ying,Ma Li,Jin Ri-Zhe,&Gao Lian-Xun.(2006).Synthesis and charaterization of Ru complex with terpyridine on quartz substrates surface.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,27(12),2337-2339. |
| MLA | Zhao Jian-Ying,et al."Synthesis and charaterization of Ru complex with terpyridine on quartz substrates surface".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 27.12(2006):2337-2339. |
入库方式： OAI收割
来源：化学研究所
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