Synthesis of bis(2,2 ': 6 ',2 ''-terpyridine)-terminated telechelic polymers by RAFT polymerization and ruthenium-polymer complexation thereof
文献类型：期刊论文
| 作者 | Zhang, Liwei; Zhang, Yanhong; Chen, Yongming |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2006-10-01 |
| 卷号 | 42期号:10页码:2398-2406 |
| 关键词 | Reversible Addition-fragmentation Chain Transfer (Raft) Polymerization Supramolecular Metallo-polymers Telechelic Polymers |
| ISSN号 | 0014-3057 |
| DOI | 10.1016/j.eurpolymj.2006.05.017 |
| 英文摘要 | Well-defined polystyrenes and poly(n-butyl acrylate)s of the two ends being functionalized with terpyridine groups were synthesized via addition-fragmentation chain transfer (RAFT) polymerization using a symmetric bisterpyridine-functionalized trithiocarbonate as a chain transfer agent (CTA). Kinetic studies on RAFT mediated thermal polymerization of styrene indicated the controlled polymerization. Corresponding triblock copolymers of styrene and n-butyl acrylate were obtained by utilizing the bisterpyridine-functionalized homopolymers as the macro-CTAs. Supramolecular metallo-polystyrenes with different repeat blocks were prepared by the chelating interaction between the terpyridine ends and Ru(II) ions. The formation of the metallo-polymers was proven by UV-vis spectra and dynamic light scattering (DLS). (c) 2006 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000241460100023 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59713]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Yongming |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Liwei,Zhang, Yanhong,Chen, Yongming. Synthesis of bis(2,2 ': 6 ',2 ''-terpyridine)-terminated telechelic polymers by RAFT polymerization and ruthenium-polymer complexation thereof[J]. EUROPEAN POLYMER JOURNAL,2006,42(10):2398-2406. |
| APA | Zhang, Liwei,Zhang, Yanhong,&Chen, Yongming.(2006).Synthesis of bis(2,2 ': 6 ',2 ''-terpyridine)-terminated telechelic polymers by RAFT polymerization and ruthenium-polymer complexation thereof.EUROPEAN POLYMER JOURNAL,42(10),2398-2406. |
| MLA | Zhang, Liwei,et al."Synthesis of bis(2,2 ': 6 ',2 ''-terpyridine)-terminated telechelic polymers by RAFT polymerization and ruthenium-polymer complexation thereof".EUROPEAN POLYMER JOURNAL 42.10(2006):2398-2406. |
入库方式： OAI收割
来源：化学研究所
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