Tuning the magnetic behavior via dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O
文献类型：期刊论文
| 作者 | Lu, ZL; Wang, XY; Liu, ZL; Liao, FH; Gao, S; Xiong, RG; Ma, HW; Zhang, DQ; Zhu, DB |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2006-02-06 |
| 卷号 | 45期号:3页码:999-1004 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/ic051145f |
| 英文摘要 | A new complex (1) of Prussian blue analogue with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O was prepared and characterized structurally as well as magnetically. The crystal structure of complex 1 was determined by X-ray diffraction analysis. The results indicate that complex 1 consists of a 3D cubic lattice similar to those of Mn-3[Cr(CN)(6)](2)center dot xH(2)O, Mn-3[CO(CN)(6)](2)center dot xH(2)O, Cd-3[Cr(CN)(6)](2)center dot xH(2)O, and Cd-3[CO(CN)(6)](2)center dot xH(2)O, Magnetic measurements show that complex 1 is a ferrimagnet with T-c = 66 K. It is interesting to note that the magnetic behavior of complex 1 can be substantially modulated through a dehydration/rehydration treatment. The T-c value of this ferrimagnet increases to 99 K after dehydration reaching a 23.4% weight loss, and it decreases back to 66 K after the dehydrated sample reabsorbs water molecules. |
| 语种 | 英语 |
| WOS记录号 | WOS:000235198400012 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59741]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao, S |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing 100080, Peoples R China 2.Peking Univ, Coll Chem, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 3.Nanjing Univ, Coll Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, ZL,Wang, XY,Liu, ZL,et al. Tuning the magnetic behavior via dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O[J]. INORGANIC CHEMISTRY,2006,45(3):999-1004. |
| APA | Lu, ZL.,Wang, XY.,Liu, ZL.,Liao, FH.,Gao, S.,...&Zhu, DB.(2006).Tuning the magnetic behavior via dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O.INORGANIC CHEMISTRY,45(3),999-1004. |
| MLA | Lu, ZL,et al."Tuning the magnetic behavior via dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O".INORGANIC CHEMISTRY 45.3(2006):999-1004. |
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来源：化学研究所
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