Synthesis, rheology, and morphology of nylon-11/layered silicate nanocomposite
文献类型：期刊论文
| 作者 | Zhang, Xikui; Yang, Guisheng; Lin, Jiaping |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
 |
| 出版日期 | 2006-08-01 |
| 卷号 | 44期号:15页码:2161-2172 |
| 关键词 | In Situ Polymerization Morphology Nanocomposites Nylon-11 Rheology |
| ISSN号 | 0887-6266 |
| DOI | 10.1002/polb.20881 |
| 英文摘要 | Exfoliated nylon-11/layered silicate nanocomposites were prepared via in situ polymerization by dispersing organoclay in 11-aminoundecanoic acid monomer. The original clay was modified by a novel method with 11-aminoundecanoic acid. In situ Fourier transform infrared spectroscopy results show that stronger hydrogen bonds exist between nylon-11 and organoclay than that of between nylon-11 and original clay. The linear dynamic viscoelasticity of organoclay nanocomposites was investigated. Before taking rheological measurements, the exfoliated and intercalating structures and the thermal properties were characterized using X-ray diffraction, transmission electron microscopy, differential scanning calorimetry, and thermogravimetric analysis. The results show that the clay was uniformly distributed in nylon-11 matrix during in situ polymerization of clay with 4 wt % or less. The presence of clay in nylon-11 matrix increased the crystallization temperature and the thermal stability of nanocomposites prepared. Rheological properties such as storage modulus, loss modulus, and relative viscosity have close relationship with the dispersion favorably compatible with the organically modified clay. Comparing with neat nylon-11, the nanocomposites show much higher dynamic modulus and stronger shear thinning behavior. (c) 2006 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000239183300014 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59759]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Guisheng |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100080, Peoples R China 2.E China Univ Sci & Technol, Mat Sci & Engn Inst, Shanghai 200237, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xikui,Yang, Guisheng,Lin, Jiaping. Synthesis, rheology, and morphology of nylon-11/layered silicate nanocomposite[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2006,44(15):2161-2172. |
| APA | Zhang, Xikui,Yang, Guisheng,&Lin, Jiaping.(2006).Synthesis, rheology, and morphology of nylon-11/layered silicate nanocomposite.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,44(15),2161-2172. |
| MLA | Zhang, Xikui,et al."Synthesis, rheology, and morphology of nylon-11/layered silicate nanocomposite".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 44.15(2006):2161-2172. |
入库方式： OAI收割
来源：化学研究所
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