Synthesis, spectra, structure and quantum chemistry study on two novel oxovanadium complexes with hydrotris (pyrazolyl) borate ligands
文献类型：期刊论文
| 作者 | Xing Yongheng; Sun Zheng; Yuan Houqun; Ge Maofa; Niu Shuyun; Bai Fengying |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2006-03-01 |
| 卷号 | 51期号:6页码:661-667 |
| 关键词 | Oxovanadium Complexes Tris(Pyrazolyl)Hydroborate Spectrum Crystal Structure Quantum Calculation |
| ISSN号 | 1001-6538 |
| DOI | 10.1007/s11434-006-0661-z |
| 英文摘要 | Two novel oxo-vanadium complexes of VO(HB(pz)(3))(pzH)(SCN) (1) and VO(HB(3,5-Me(2)pz)(3)) (3,5-Me(2)pzH)(SCN)(SCNH)(2) (2) with tris(pyrazolyl) hydroborate ligands were prepared by the reaction of VOSO(4)(.)nH(2)O, KSCN with Na(HB(pz)(3)), pyrazole, or Na(HB(3,5-Me(2)PZ)(3)) and methyl-substituted pyrazole in the solution of MeOH, respectively. The complexes were characterized by element analysis, IR, and UV-vis spectra. In the mean time, the fluorescence spectrum was studied too, and the result indicates that the luminescence of the complexes is related to the interaction between oxovanadium ion and tris(pyrazolyl) hydroborate ligands. In addition, structures of oxovanadium complexes 1 and 2 were determined by X-ray diffraction. The electronic structures and the bonding characters of the two complexes were analyzed with ab initio calculations. |
| 语种 | 英语 |
| WOS记录号 | WOS:000237619400004 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59909]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing Yongheng |
| 作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xing Yongheng,Sun Zheng,Yuan Houqun,et al. Synthesis, spectra, structure and quantum chemistry study on two novel oxovanadium complexes with hydrotris (pyrazolyl) borate ligands[J]. CHINESE SCIENCE BULLETIN,2006,51(6):661-667. |
| APA | Xing Yongheng,Sun Zheng,Yuan Houqun,Ge Maofa,Niu Shuyun,&Bai Fengying.(2006).Synthesis, spectra, structure and quantum chemistry study on two novel oxovanadium complexes with hydrotris (pyrazolyl) borate ligands.CHINESE SCIENCE BULLETIN,51(6),661-667. |
| MLA | Xing Yongheng,et al."Synthesis, spectra, structure and quantum chemistry study on two novel oxovanadium complexes with hydrotris (pyrazolyl) borate ligands".CHINESE SCIENCE BULLETIN 51.6(2006):661-667. |
入库方式： OAI收割
来源：化学研究所
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