Competition between band filling and steric effect in ordered double perovskites Sr2-xLaxMnMoO6
文献类型：期刊论文
| 作者 | Tian Shizhe; Zhao Junchai; Qiao Congde; Ji Xiangling; Jiang Bingzheng |
| 刊名 | JOURNAL OF RARE EARTHS
 |
| 出版日期 | 2006-12-01 |
| 卷号 | 24期号:6页码:679-684 |
| 关键词 | Double Perovskite Band Filling Steric Effect Ferrimagnetism Rare Earths |
| ISSN号 | 1002-0721 |
| 英文摘要 | The ordered double perovskites, Sr2-xLaxMnMoO6, were prepared by sol-gel reaction. Structural, magnetic, and electrical properties were investigated for a series of ordered double perovskites Sr2-xLaxMnMoO6(0 <= x <= 1). The compounds have a monoclinic structure (space group P2(1)/n) and the cell volume expands monotonically with La doping. The T-C and the magnetic moment rise and the cusp-like transition temperature below which the magnetic frustration occurs shifts to high temperature as x increases. With La doping, electrical resistivity of Sr2-xLaxMnMoO6 decreases only at low doping levels (x <= 0.2); while at high doping levels (0.8 <= x <= 1), electrical resistivity tends to increase greatly. The results suggest that the competition between band filling effect and steric effect coexists in the whole doping range, and the formation of ferrimagnetic interactions is not simply at the expense of antiferromagnetic interactions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000243319700008 |
| 出版者 | METALLURGICAL INDUSTRY PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60045]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tian Shizhe |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian Shizhe,Zhao Junchai,Qiao Congde,et al. Competition between band filling and steric effect in ordered double perovskites Sr2-xLaxMnMoO6[J]. JOURNAL OF RARE EARTHS,2006,24(6):679-684. |
| APA | Tian Shizhe,Zhao Junchai,Qiao Congde,Ji Xiangling,&Jiang Bingzheng.(2006).Competition between band filling and steric effect in ordered double perovskites Sr2-xLaxMnMoO6.JOURNAL OF RARE EARTHS,24(6),679-684. |
| MLA | Tian Shizhe,et al."Competition between band filling and steric effect in ordered double perovskites Sr2-xLaxMnMoO6".JOURNAL OF RARE EARTHS 24.6(2006):679-684. |
入库方式： OAI收割
来源：化学研究所
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