Preparation and properties of composites of thermotropic liquid crystalline copolyesters and polyester thermoplastic elastomer
文献类型：期刊论文
| 作者 | Li, J; Wu, MY |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2006-02-01 |
| 期号 | 1页码:102-107 |
| 关键词 | In Situ Polycondensation Method Thermal Liquid Crystalline Eopolyesters Polyester Thermoplastic Elastomer Composites |
| ISSN号 | 1000-3304 |
| 英文摘要 | The composites of thermotropic liquid crystalline copolyesters ((p-hydroxy benzoic acid) -terephthalic acid-resorcin) (HB-TA-RES) and poly(butylene terephthalate) -poly( tetramethylene glycol) thermoplastic elastomer (PBT-PTMG) with different copolyester content or copolyester composition were prepared by in-situ polycondensation method. The obtained (HB-TA-RES)/PBT-PTMG were characterized by POM,TGA,WAXD,SEM and theological analysis. Liquid crystalline behavior of the composites was observed when the 1413 content in copolyester was 40 mol% and copolyester content in composite was 30 wt% similar to 70 wt% or copolyester content in composite was around 50 wt% and HB content in copolyester was 20 mol% 80 mol%. When the copolyester content in composites <= 50 wt % or HB content in copolyester <= 60 mol %, no obvious phase separation happened. The molecular structure of copolyester in composites was more homogeneous and the crystallization of HB was limited. The good thermal stability of ( HB-TA-RES)/PBT-PTMG composites with thermotropic liquid crystalline behavior was obtained as compared with the corresponding homocopolyester and the viscosity of the composites was lower than that of the matrix PBT-PTMG especially when the copolyester content was more than 30 wt%. Good processability of the composite is expected in the application. |
| 语种 | 英语 |
| WOS记录号 | WOS:000235419800020 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60113]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, J |
| 作者单位 | 1.Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, J,Wu, MY. Preparation and properties of composites of thermotropic liquid crystalline copolyesters and polyester thermoplastic elastomer[J]. ACTA POLYMERICA SINICA,2006(1):102-107. |
| APA | Li, J,&Wu, MY.(2006).Preparation and properties of composites of thermotropic liquid crystalline copolyesters and polyester thermoplastic elastomer.ACTA POLYMERICA SINICA(1),102-107. |
| MLA | Li, J,et al."Preparation and properties of composites of thermotropic liquid crystalline copolyesters and polyester thermoplastic elastomer".ACTA POLYMERICA SINICA .1(2006):102-107. |
入库方式： OAI收割
来源：化学研究所
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