1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude
文献类型：期刊论文
| 作者 | Xiao, Fengping; Wang, Jianbo |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2006-07-21 |
| 卷号 | 71期号:15页码:5789-5791 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/jo0605391 |
| 英文摘要 | A series of diazo carbonyl compounds bearing different substituents have been prepared in order to investigate the steric effect in 1,2-migration reaction of rhodium(II) carbene. Through the investigation on the diazo decomposition of these compounds with Rh-2(OAc)(4), it was found that the steric effect could dramatically influence the migratory aptitude. In many cases, the steric effect could override the inherent electronic effect of the substituent. |
| 语种 | 英语 |
| WOS记录号 | WOS:000239017500049 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60189]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Fengping,Wang, Jianbo. 1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude[J]. JOURNAL OF ORGANIC CHEMISTRY,2006,71(15):5789-5791. |
| APA | Xiao, Fengping,&Wang, Jianbo.(2006).1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude.JOURNAL OF ORGANIC CHEMISTRY,71(15),5789-5791. |
| MLA | Xiao, Fengping,et al."1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude".JOURNAL OF ORGANIC CHEMISTRY 71.15(2006):5789-5791. |
入库方式： OAI收割
来源：化学研究所
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