中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Structure and properties of polypropylene alloy in situ blends

文献类型:期刊论文

作者Cui, NN; Ke, YC; Lu, ZX; Wu, CH; Hu, YL
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2006-06-15
卷号100期号:6页码:4804-4810
关键词Polypropylene (Pp) Alloy Toughness Ziegler-natta Catalyst Ethylene-propylene Copolymer Diether
ISSN号0021-8995
DOI10.1002/app.23459
英文摘要A series of polypropylene (PP) alloys containing different ethylene contents have been prepared by the in situ sequential polymerization technique, using Ziegler-Natta catalyst (MgCl2/TiCl4/BMF; BMF is 9,9-bis-(methoxymethyl)fluorine, as an internal donor) without any external donor. The structure and properties of PP alloys obtained have been investigated by nuclear magnetic resonance, Fourier transform infrared spectroscopy, dynamic mechanical analysis, differential scanning calorimetry, and scanning electron microscopy (SEM). The results have suggested that PP alloys are the complex Mixtures containing PP, the copolymer with long sequence ethylene chain, ethylene-propylene rubber (EPR), and block copolymer etc. In the alloys, PP, EPR, and the copolymer with long sequence ethylene chain are partially compatible. The investigation of the mechanical propertied indicates that notched Izod impact strength of PP alloy greatly increases at 16 degrees C/-20 degrees C in comparison with that of pure PP. The noticeable plastic deformation is observed in SEM photograph. The increase in the toughness, the mechanical strength of PP alloy decreases to a certain extent. (c) 2006 Wiley Periodicals, Inc.
语种英语
WOS记录号WOS:000237126900069
出版者JOHN WILEY & SONS INC
源URL[http://ir.iccas.ac.cn/handle/121111/60239]  
专题中国科学院化学研究所
通讯作者Hu, YL
作者单位1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, CAS,Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
推荐引用方式
GB/T 7714
Cui, NN,Ke, YC,Lu, ZX,et al. Structure and properties of polypropylene alloy in situ blends[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2006,100(6):4804-4810.
APA Cui, NN,Ke, YC,Lu, ZX,Wu, CH,&Hu, YL.(2006).Structure and properties of polypropylene alloy in situ blends.JOURNAL OF APPLIED POLYMER SCIENCE,100(6),4804-4810.
MLA Cui, NN,et al."Structure and properties of polypropylene alloy in situ blends".JOURNAL OF APPLIED POLYMER SCIENCE 100.6(2006):4804-4810.

入库方式: OAI收割

来源:化学研究所

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