Determination of the formation of dark state via depleted spontaneous emission in a complex solvated molecule
文献类型：期刊论文
| 作者 | Guo, Xunmin; Wang, Sufan; Xia, Andong; Su, Hongmei |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2007-07-05 |
| 卷号 | 111期号:26页码:5800-5805 |
| ISSN号 | 1089-5639 |
| DOI | 10.1021/jp070531a |
| 英文摘要 | We present a general two-color two-pulse femtosecond pump-dump approach to study the specific population transfer along the reaction coordinate through the higher vibrational energy levels of excited states of a complex solvated molecule via the depleted spontaneous emission. The time-dependent fluorescence depletion provides the correlated dynamical information between the monitored fluorescence state and the SEP "dumped" dark states, and therefore allow us to obtain the dynamics of the formation of the dark states corresponding to the ultrafast photoisomerization processes. The excited-state dynamics of LDS 751 have been investigated as a function of solvent viscosity and solvent polarity, where a cooperative two-step isomerization process is clearly identified within LDS 751 upon excitation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000247573600026 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60315]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xia, Andong |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China 2.Chinese Acad Sci, BNLMS, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Xunmin,Wang, Sufan,Xia, Andong,et al. Determination of the formation of dark state via depleted spontaneous emission in a complex solvated molecule[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2007,111(26):5800-5805. |
| APA | Guo, Xunmin,Wang, Sufan,Xia, Andong,&Su, Hongmei.(2007).Determination of the formation of dark state via depleted spontaneous emission in a complex solvated molecule.JOURNAL OF PHYSICAL CHEMISTRY A,111(26),5800-5805. |
| MLA | Guo, Xunmin,et al."Determination of the formation of dark state via depleted spontaneous emission in a complex solvated molecule".JOURNAL OF PHYSICAL CHEMISTRY A 111.26(2007):5800-5805. |
入库方式： OAI收割
来源：化学研究所
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