Intramolecular electron transfer within the substituted tetrathiafulvalene-quinone dyads: Facilitated by metal ion and photomodulation in the presence of spiropyran
文献类型：期刊论文
| 作者 | Wu, Hui; Zhang, Deqing; Su, Lei; Ohkubo, Kei; Zhang, Chunxi; Yin, Shiwei; Mao, Lanqun; Shuai, Zhigang; Fukuzumi, Shunichi; Zhu, Daoben |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2007-05-30 |
| 卷号 | 129期号:21页码:6839-6846 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja0702824 |
| 英文摘要 | Intramolecular electron transfer is observed for two new substituted tetrathiafulvalene (TTF)-quinone dyads 1 and 2 in the presence of metal ions. On the basis of the electrochemical studies of reference compound 5 and the comparative studies with dyad 3, it was proposed that the synergic coordination of the radical anion of quinone and the oligoethylene glycol chain with metal ions may be responsible for stabilizing the charge-separation state and thus facilitating the electron-transfer process. Most interestingly, the intramolecular electron-transfer processes within these two dyads can be modulated by UV-vis light irradiation in the presence of spiropyran, by taking advantage of its unique properties. |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000246686700044 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60353]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Deqing |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Div Adv Sci & Biotechnol,SORST, Suita, Osaka 5650871, Japan |
| 推荐引用方式 GB/T 7714 | Wu, Hui,Zhang, Deqing,Su, Lei,et al. Intramolecular electron transfer within the substituted tetrathiafulvalene-quinone dyads: Facilitated by metal ion and photomodulation in the presence of spiropyran[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2007,129(21):6839-6846. |
| APA | Wu, Hui.,Zhang, Deqing.,Su, Lei.,Ohkubo, Kei.,Zhang, Chunxi.,...&Zhu, Daoben.(2007).Intramolecular electron transfer within the substituted tetrathiafulvalene-quinone dyads: Facilitated by metal ion and photomodulation in the presence of spiropyran.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,129(21),6839-6846. |
| MLA | Wu, Hui,et al."Intramolecular electron transfer within the substituted tetrathiafulvalene-quinone dyads: Facilitated by metal ion and photomodulation in the presence of spiropyran".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129.21(2007):6839-6846. |
入库方式： OAI收割
来源：化学研究所
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