Investigation of the gel effect in reactive extrusion processes for free radical polymerization
文献类型:期刊论文
作者 | Zhang, Guofang; Jia, Yuxi; Sun, Sheng; Wu, Lili; Zhao, Guoqun; An, Lijia |
刊名 | MACROMOLECULAR REACTION ENGINEERING
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出版日期 | 2007-05-08 |
卷号 | 1期号:3页码:321-330 |
关键词 | Free Radical Polymerization Gel Effect Numerical Simulation Reactive Extrusion |
ISSN号 | 1862-832X |
DOI | 10.1002/mren.200600030 |
英文摘要 | The gel effect in the reactive extrusion process for free radical polymerization in a closely intermeshing co-rotating twin screw extruder was investigated. First the reaction kinetic model was constructed mainly on the basis of entanglement theory. Next, numerical calculation expressions for the initiator and monomer concentrations, monomer conversion, average molecular weight and apparent viscosity were deduced. Finally, the evolution of the above variables were shown and discussed for the example of butyl methacrylate. The simulated results of the monomer conversion are in good agreement with experimental results. |
语种 | 英语 |
WOS记录号 | WOS:000250202300003 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/60377] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Jia, Yuxi |
作者单位 | 1.Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Guofang,Jia, Yuxi,Sun, Sheng,et al. Investigation of the gel effect in reactive extrusion processes for free radical polymerization[J]. MACROMOLECULAR REACTION ENGINEERING,2007,1(3):321-330. |
APA | Zhang, Guofang,Jia, Yuxi,Sun, Sheng,Wu, Lili,Zhao, Guoqun,&An, Lijia.(2007).Investigation of the gel effect in reactive extrusion processes for free radical polymerization.MACROMOLECULAR REACTION ENGINEERING,1(3),321-330. |
MLA | Zhang, Guofang,et al."Investigation of the gel effect in reactive extrusion processes for free radical polymerization".MACROMOLECULAR REACTION ENGINEERING 1.3(2007):321-330. |
入库方式: OAI收割
来源:化学研究所
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