中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Investigation of the gel effect in reactive extrusion processes for free radical polymerization

文献类型:期刊论文

作者Zhang, Guofang; Jia, Yuxi; Sun, Sheng; Wu, Lili; Zhao, Guoqun; An, Lijia
刊名MACROMOLECULAR REACTION ENGINEERING
出版日期2007-05-08
卷号1期号:3页码:321-330
关键词Free Radical Polymerization Gel Effect Numerical Simulation Reactive Extrusion
ISSN号1862-832X
DOI10.1002/mren.200600030
英文摘要The gel effect in the reactive extrusion process for free radical polymerization in a closely intermeshing co-rotating twin screw extruder was investigated. First the reaction kinetic model was constructed mainly on the basis of entanglement theory. Next, numerical calculation expressions for the initiator and monomer concentrations, monomer conversion, average molecular weight and apparent viscosity were deduced. Finally, the evolution of the above variables were shown and discussed for the example of butyl methacrylate. The simulated results of the monomer conversion are in good agreement with experimental results.
语种英语
WOS记录号WOS:000250202300003
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.iccas.ac.cn/handle/121111/60377]  
专题中国科学院化学研究所
通讯作者Jia, Yuxi
作者单位1.Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Guofang,Jia, Yuxi,Sun, Sheng,et al. Investigation of the gel effect in reactive extrusion processes for free radical polymerization[J]. MACROMOLECULAR REACTION ENGINEERING,2007,1(3):321-330.
APA Zhang, Guofang,Jia, Yuxi,Sun, Sheng,Wu, Lili,Zhao, Guoqun,&An, Lijia.(2007).Investigation of the gel effect in reactive extrusion processes for free radical polymerization.MACROMOLECULAR REACTION ENGINEERING,1(3),321-330.
MLA Zhang, Guofang,et al."Investigation of the gel effect in reactive extrusion processes for free radical polymerization".MACROMOLECULAR REACTION ENGINEERING 1.3(2007):321-330.

入库方式: OAI收割

来源:化学研究所

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