Spectroscopic studies of tris(2,2 '-bipyridine)ruthenium(II) intercalated to modified alpha-zirconium phosphate
文献类型：期刊论文
| 作者 | Shi, Shikao; Zhou, Ji; Zong, Ruilong; Ye, Jianping |
| 刊名 | JOURNAL OF LUMINESCENCE
 |
| 出版日期 | 2007 |
| 卷号 | 122页码:218-220 |
| 关键词 | Luminescence Intercalation Alpha-zirconium Phosphate Tris(2 2 '-bipyridine)Ruthenium(Ii) |
| ISSN号 | 0022-2313 |
| DOI | 10.1016/j.jlumin.2006.01.095 |
| 英文摘要 | This paper presented the absorption and fluorescence spectra as well as luminescence lifetime of tris(2,2'-bipyridine)ruthenium(II) (abbreviated as Ru(bpy)(3)(2+)) intercalated to modified alpha-zirconium phosphate in aqueous media. The results showed extensive red shifts of the absorption band of the metal complex (from 454 to 482nm) and blue shifts of the emission maximum (from 610 to 582nm) as compared to that of free chromophore. On the other hand, the luminescence intensities and the excited-state lifetimes of the metal complex were dramatically increased. X-ray diffraction (XRD) patterns of the powder samples indicated that intercalation of Ru(bpy)(3)(2+) into modified alpha-zirconium phosphate reduced somewhat the interlayer separation from 18.6 to 17.1 angstrom. In addition, spectroscopic measurements for Ru(bpy)(2+)(3) with modified alpha-zirconium phosphate in ethanol media were also proceeded. No significant difference was observed, which implied that Ru(bpy)(3)(2+) could not enter into modified alpha-zirconiunt phosphate in ethanol media. (c) 2006 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000242991900065 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60395]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhou, Ji |
| 作者单位 | 1.Tsing Hua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China 2.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Shikao,Zhou, Ji,Zong, Ruilong,et al. Spectroscopic studies of tris(2,2 '-bipyridine)ruthenium(II) intercalated to modified alpha-zirconium phosphate[J]. JOURNAL OF LUMINESCENCE,2007,122:218-220. |
| APA | Shi, Shikao,Zhou, Ji,Zong, Ruilong,&Ye, Jianping.(2007).Spectroscopic studies of tris(2,2 '-bipyridine)ruthenium(II) intercalated to modified alpha-zirconium phosphate.JOURNAL OF LUMINESCENCE,122,218-220. |
| MLA | Shi, Shikao,et al."Spectroscopic studies of tris(2,2 '-bipyridine)ruthenium(II) intercalated to modified alpha-zirconium phosphate".JOURNAL OF LUMINESCENCE 122(2007):218-220. |
入库方式： OAI收割
来源：化学研究所
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