Highly efficient asymmetric hydrogenation of alpha,beta-unsaturated carboxylic acids catalyzed by ruthenium(II)-dipyridylphosphine complexes
文献类型：期刊论文
| 作者 | Qiu, Liqin; Li, Yue-Ming; Kwong, Fuk Yee; Yu, Wing-Yiu; Fan, Qing-Hua; Chan, Albert S. C. |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2007-03-01 |
| 卷号 | 349期号:4-5页码:517-520 |
| 关键词 | Asymmetric Hydrogenation Dipyridylphosphine P-phos Ruthenium Complexes Xyl-p-phos Alpha Beta-unsaturated Carboxylic Acids |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.200600410 |
| 英文摘要 | Two types of catalysts [RuL(benzene)Cl]Cl and Ru(OCOCH3)(2)L with the dipyridylphosphine ligands P-Phos and Xyl-P-Phos were applied in the asymmetric hydrogenation of alpha,beta-unsaturated carboxylic acids. The cationic complexes [RuL(benzene)Cl]Cl were found to be superior to the corresponding neutral complex Ru(OCOCH3)(2)L in this type of reactions. The catalysts exhibited excellent activities and enantioselectivities (up to 97% ee) in the asymmetric hydrogenation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000245379400006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60397]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chan, Albert S. C. |
| 作者单位 | 1.State Key Lab Chinese Med & Mol Pharmacol, Shenzhen, Peoples R China 2.Hong Kong Polytech Univ, Inst Mol Technol Drug Discovery & Synth, Open Lab Chirotechnol, Kowloon, Hong Kong, Peoples R China 3.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China 4.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiu, Liqin,Li, Yue-Ming,Kwong, Fuk Yee,et al. Highly efficient asymmetric hydrogenation of alpha,beta-unsaturated carboxylic acids catalyzed by ruthenium(II)-dipyridylphosphine complexes[J]. ADVANCED SYNTHESIS & CATALYSIS,2007,349(4-5):517-520. |
| APA | Qiu, Liqin,Li, Yue-Ming,Kwong, Fuk Yee,Yu, Wing-Yiu,Fan, Qing-Hua,&Chan, Albert S. C..(2007).Highly efficient asymmetric hydrogenation of alpha,beta-unsaturated carboxylic acids catalyzed by ruthenium(II)-dipyridylphosphine complexes.ADVANCED SYNTHESIS & CATALYSIS,349(4-5),517-520. |
| MLA | Qiu, Liqin,et al."Highly efficient asymmetric hydrogenation of alpha,beta-unsaturated carboxylic acids catalyzed by ruthenium(II)-dipyridylphosphine complexes".ADVANCED SYNTHESIS & CATALYSIS 349.4-5(2007):517-520. |
入库方式： OAI收割
来源：化学研究所
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