[Fe-3(HCOO)(6)]: A permanent porous diamond framework displaying H-2/N-2 adsorption, guest inclusion, and guest-dependent magnetism
文献类型：期刊论文
| 作者 | Wang, Zheming; Zhang, Yanjuan; Liu, Tao; Kurmoo, Mohamedally; Gao, Song |
| 刊名 | ADVANCED FUNCTIONAL MATERIALS
 |
| 出版日期 | 2007-06-18 |
| 卷号 | 17期号:9页码:1523-1536 |
| ISSN号 | 1616-301X |
| DOI | 10.1002/adfm.200600676 |
| 英文摘要 | The porous magnet [Fe-3(HCOO)(6)], the iron member of the [M-3(HCOO)(6)] family (where M = Mn, Fe, Co, Ni, etc.), based on a diamond framework consisting of Fe-centered FeFe4 tetrahedral nodes, is prepared successfully by using a solution-chemistry method. The as-prepared compound, [Fe-3(HCOO)(6)](CH3OH)(1.5)(H2O)(0.5) (1-parent), exhibits facile removal of its guests, methanol, and water, to give the desolvated framework [Fe-3(HCOO)(6)] (2-empty) that displays permanent porosity and thermal stability up to 270 degrees C. The flexibility of the framework and the amphiphilic nature of the surface of the pores consisting of both C-H and 0 arrays allows 2-empty to take up significant H-2 and N-2 at liquid-nitrogen temperatures and a wide spectrum of both polar and non-polar guests of different sizes. A series of guest-inclusion compounds, [Fe-3(HCOO)(6)](I-2)(0.64) (3-iodine), [Fe-3(HCOO)(6)](C4H8O) (4-THF), [Fe-3(HCOO)(6)](C4H4O) (5-furan), [Fe-3(HCOO)(6)](C6H6) (6-benzene), [Fe-3(HCOO)(6)](CH3CN) (7-acetonitrille), and [Fe-3(HCOO)(6)]((CH3)(2)CO) (8-acetone) are successfully prepared by vapor diffusion of the guest into the pores of 2-empty and their structures are characterized by using single-crystal X-ray crystallography. Zigzag molecular arrays of the guest are formed in the confined channels of the host framework, and the weak hydrogen-bonding provides the main host-guest interaction. All the compounds show 3D long-range magnetic ordering and guest-modulated Curie temperatures, coercive fields, and remnant magnetization as a consequence of the subtle rearrangement of the magnetic framework that conforms to the size of the guests and the difference in host-guest interactions. A possible magnetic structure of the framework is proposed to account for magnetic competition and geometrical frustration. The thermal and spectroscopic properties of the compounds are also reported. |
| 语种 | 英语 |
| WOS记录号 | WOS:000247806300012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60405]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Zheming |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Univ Strasbourg 1, Chim Coordinat Organ Lab, Inst Le Bel, UMR7140, F-67000 Strasbourg 01, France |
| 推荐引用方式 GB/T 7714 | Wang, Zheming,Zhang, Yanjuan,Liu, Tao,et al. [Fe-3(HCOO)(6)]: A permanent porous diamond framework displaying H-2/N-2 adsorption, guest inclusion, and guest-dependent magnetism[J]. ADVANCED FUNCTIONAL MATERIALS,2007,17(9):1523-1536. |
| APA | Wang, Zheming,Zhang, Yanjuan,Liu, Tao,Kurmoo, Mohamedally,&Gao, Song.(2007).[Fe-3(HCOO)(6)]: A permanent porous diamond framework displaying H-2/N-2 adsorption, guest inclusion, and guest-dependent magnetism.ADVANCED FUNCTIONAL MATERIALS,17(9),1523-1536. |
| MLA | Wang, Zheming,et al."[Fe-3(HCOO)(6)]: A permanent porous diamond framework displaying H-2/N-2 adsorption, guest inclusion, and guest-dependent magnetism".ADVANCED FUNCTIONAL MATERIALS 17.9(2007):1523-1536. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。