Synthesis, structure and thermal properties of [HN(C2H5)(3)] [B5O6(OH)(4)]
文献类型:期刊论文
作者 | Yang Zi-Liang; Yang Si-Hai; Li Guo-Bao; Lin Jian-Hua |
刊名 | ACTA PHYSICO-CHIMICA SINICA
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出版日期 | 2007-03-01 |
卷号 | 23期号:3页码:285-288 |
关键词 | Crystal Structure Triethylamine Pentaborate Hydrothermal Reaction |
ISSN号 | 1000-6818 |
DOI | 10.1016/S1872-1508(07)60020-5 |
英文摘要 | Triethylamine pentaborate, [HN(C2H5)(3)]B5O6(OH)(4)] (1), was hydrothermally synthesized and characterized by single crystal X-ray diffraction, FTIR, elemental analysis, and thermogravimetric analysis. Compound 1 crystallized in the monoclinic system, space group P2(1)/c with a=1.0036(2) nm, b=1.1353(2) nm, c=1.4843(3) nm, and beta=106.54(3)degrees. It consisted of isolated borate polyanion [B5O6(OH)(4)](-) and triethylamine cation [HN(C2H5)(3)](+). The anionic units, [B5O6(OH)(4)](-), were linked by hydrogen bonds to form a 3D supramolecular network containing large channels, in which the templating [HN(C2H5)(3)](+) cations were located. |
语种 | 英语 |
WOS记录号 | WOS:000245164200001 |
出版者 | PEKING UNIV PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/60453] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li Guo-Bao |
作者单位 | Peking Univ, Coll Chem & Mol Engn, BNLMS, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Yang Zi-Liang,Yang Si-Hai,Li Guo-Bao,et al. Synthesis, structure and thermal properties of [HN(C2H5)(3)] [B5O6(OH)(4)][J]. ACTA PHYSICO-CHIMICA SINICA,2007,23(3):285-288. |
APA | Yang Zi-Liang,Yang Si-Hai,Li Guo-Bao,&Lin Jian-Hua.(2007).Synthesis, structure and thermal properties of [HN(C2H5)(3)] [B5O6(OH)(4)].ACTA PHYSICO-CHIMICA SINICA,23(3),285-288. |
MLA | Yang Zi-Liang,et al."Synthesis, structure and thermal properties of [HN(C2H5)(3)] [B5O6(OH)(4)]".ACTA PHYSICO-CHIMICA SINICA 23.3(2007):285-288. |
入库方式: OAI收割
来源:化学研究所
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