Synthesis, structure and luminescence properties of zinc (II) complexes with terpyridine derivatives as ligands
文献类型：期刊论文
| 作者 | Chen, Xuegang; Zhou, Quanguo; Cheng, Yanxiang; Geng, Yanhou; Ma, Dongge; Xie, Zhiyuan; Wang, Lixiang |
| 刊名 | JOURNAL OF LUMINESCENCE
 |
| 出版日期 | 2007-09-01 |
| 卷号 | 126期号:1页码:81-90 |
| 关键词 | Terpyridine Derivatives Zinc Complexes Donor Acceptor Solvatochromism Electroluminescence |
| ISSN号 | 0022-2313 |
| DOI | 10.1016/j.jlumin.2006.05.008 |
| 英文摘要 | Five zinc (II) complexes (1-5) with 4 '-phenyl-2,2 ':6 ',2 ''-terpyridine (ptpy) derivatives as ligands have been synthesized and fully characterized. The para-position of phenyl in ptpy is substituted by the group (R), i.e. tert-butyl (t-Bu), hexyloxy (OHex), carbazole-9-yl (Cz), naphthalen-1-yl-phenyl-amine-N-yl (NPA) and diphenyl amine-N-yl (DPA), with different electron-donating ability. With increasing donor ability of the R, the emission color of the complexes in film was modulated from violet (392 nm) to reddish orange (604 nm). The photoexcited luminescence exhibits significant solvatochromism because the emission of the complexes involves the intra-ligand charge transfer (ILCT) excited state. The electrochemical investigations show that the complexes with stronger electro-donating substituent have lower oxidation potential and then higher HOMO level. The electroluminescence (EL) properties of these zinc (II) complexes were studied with the device structure of ITO/PEDOT/Zn (II) complex: PBD:PMMA/BCP/AlQ/ LiF/Al. Complexes 3, 4 and 5 exhibit EL wavelength at 552, 600 and 609 nm with maximum current efficiency of 5.28, 2.83 and 2.00 cd/A, respectively. (C) 2006 Elsevier BN. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000246640200013 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60479]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cheng, Yanxiang |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Xuegang,Zhou, Quanguo,Cheng, Yanxiang,et al. Synthesis, structure and luminescence properties of zinc (II) complexes with terpyridine derivatives as ligands[J]. JOURNAL OF LUMINESCENCE,2007,126(1):81-90. |
| APA | Chen, Xuegang.,Zhou, Quanguo.,Cheng, Yanxiang.,Geng, Yanhou.,Ma, Dongge.,...&Wang, Lixiang.(2007).Synthesis, structure and luminescence properties of zinc (II) complexes with terpyridine derivatives as ligands.JOURNAL OF LUMINESCENCE,126(1),81-90. |
| MLA | Chen, Xuegang,et al."Synthesis, structure and luminescence properties of zinc (II) complexes with terpyridine derivatives as ligands".JOURNAL OF LUMINESCENCE 126.1(2007):81-90. |
入库方式： OAI收割
来源：化学研究所
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