中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A family of porous magnets, [M-3(HCOO)(6)] (M = Mn, Fe, Co and Ni)

文献类型:期刊论文

作者Wang, Zheming; Zhang, Bin; Zhang, Yanjuan; Kurmoo, Mohamedally; Liu, Tao; Gao, Song; Kobayashi, Hayao
刊名POLYHEDRON
出版日期2007-06-15
卷号26期号:9-11页码:2207-2215
关键词Porous Magnet Metal Formate Diamond Framework Guest Inclusion Crystal Structure Magnetism
ISSN号0277-5387
DOI10.1016/j.poly.2006.10.043
英文摘要A family of porous magnets of [M-3(HCOO)(6)] (M = Mn, Fe, Co and Ni) with open diamond framework based on M-centred MM4 tetrahedral nodes, can be prepared by conventional solution chemistry method. They display permanent porosity, stability for thermal treatment, guest removal, and guest inclusion for a wide spectrum of both polar and non-polar guests of different size. The porous magnets show 3D long-range magnetic ordering and guest-modulated magnetic properties due to the subtle structure change of the magnetic framework that conforms to the guests and the nature of host-guest interaction. The dilution of [Fe-3(HCOO)(6)] framework by diamagnetic zinc ion results in a mixed-metal porous [FexZn3-x(HCOO)(6)] series showing gradual evolution from 3D long-range ordering to spin glass then superparamagnet and finally paramagnet. (c) 2006 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000247700400077
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/60485]  
专题中国科学院化学研究所
通讯作者Wang, Zheming
作者单位1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China
3.Japan Sci & Technol Coorporat, Inst Mol Sci, Okazaki, Aichi 4448585, Japan
4.Japan Sci & Technol Coorporat, CREST, Okazaki, Aichi 4448585, Japan
5.Univ Louis Pasteur Strasbourg 1, Chim Coordinat Organ Lab, UMR7140, CNRS,Inst Le Bel, F-67000 Strasbourg 01, France
推荐引用方式
GB/T 7714
Wang, Zheming,Zhang, Bin,Zhang, Yanjuan,et al. A family of porous magnets, [M-3(HCOO)(6)] (M = Mn, Fe, Co and Ni)[J]. POLYHEDRON,2007,26(9-11):2207-2215.
APA Wang, Zheming.,Zhang, Bin.,Zhang, Yanjuan.,Kurmoo, Mohamedally.,Liu, Tao.,...&Kobayashi, Hayao.(2007).A family of porous magnets, [M-3(HCOO)(6)] (M = Mn, Fe, Co and Ni).POLYHEDRON,26(9-11),2207-2215.
MLA Wang, Zheming,et al."A family of porous magnets, [M-3(HCOO)(6)] (M = Mn, Fe, Co and Ni)".POLYHEDRON 26.9-11(2007):2207-2215.

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来源:化学研究所

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