Analysis of chemical calorific effect during reactive extrusion processes for free radical polymerization
文献类型：期刊论文
| 作者 | Jia, Yuxi; Zhan, Guofang; Wu, Lili; Sun, Sheng; Zhao, Guoqun; An, Lijia |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2007-12-01 |
| 卷号 | 56期号:12页码:1553-1557 |
| 关键词 | Reactive Extrusion Free Radical Polymerization Chemical Calorific Effect Numerical Analysis |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.2303 |
| 英文摘要 | In the reactive extrusion process for polymerization, the chemical calorific effect has a great influence on the temperature. In order to quantitatively analyze the polymerization trend and optimize the processing conditions, the phenomena of the chemical calorific effect during reactive extrusion processes for free radical polymerization were analyzed. Numerical computation expressions of the heat of chemical reaction and the reactive calorific intensity were deduced, and then a numerical simulation of the reactive extrusion process for the polymerization of n-butyl methacrylate was carried out. The evolutions of the heat of chemical reaction and the reactive calorific intensity along the! axial direction of the extruder are presented, on the basis of which reactive processing conditions can be optimized. (C) 2007 Society of Chemical Industry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000251014600011 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60501]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jia, Yuxi |
| 作者单位 | 1.Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Yuxi,Zhan, Guofang,Wu, Lili,et al. Analysis of chemical calorific effect during reactive extrusion processes for free radical polymerization[J]. POLYMER INTERNATIONAL,2007,56(12):1553-1557. |
| APA | Jia, Yuxi,Zhan, Guofang,Wu, Lili,Sun, Sheng,Zhao, Guoqun,&An, Lijia.(2007).Analysis of chemical calorific effect during reactive extrusion processes for free radical polymerization.POLYMER INTERNATIONAL,56(12),1553-1557. |
| MLA | Jia, Yuxi,et al."Analysis of chemical calorific effect during reactive extrusion processes for free radical polymerization".POLYMER INTERNATIONAL 56.12(2007):1553-1557. |
入库方式： OAI收割
来源：化学研究所
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