Study on the (HI)(m)(H(2)O)(n) clusters by photofragment translational spectroscopy and ab-initio calculation
文献类型：期刊论文
| 作者 | Bi, Weibin; Xu, Xiling; Huang, Jiangou; Xiao, Daoqing; Tang, Zichao; Zhu, Qihe |
| 刊名 | ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS
 |
| 出版日期 | 2007 |
| 卷号 | 221期号:6页码:815-824 |
| 关键词 | (Hi)(m)(h(2)o)(n) Clusters Photodissociation Photofragment Translational Spectroscopy Ab-initio Calculation |
| ISSN号 | 0942-9352 |
| DOI | 10.1524/zpch.2007.221.6.815 |
| 英文摘要 | The photodissociation of the clusters (HI)(m)(H(2)O)(n) in the supersonic molecular beam has been investigated at 281.73 nm and 280.99 nm by photofragment translational spectroscopy (PTS). The translational energy distributions of the photofragment I* ((2)P(1/2)) show that the photodissociated species is mainly HI(H(2)O)(n) (n >= 4) clusters. In addition, the structures and the relative stability of (HI)(m), (H(2)O)(n) and (HI)(m) (H(2)O)(n) (m = 1 similar to 4, n = 1 similar to 6) clusters have been obtained by ab initio calculation (the Density Functional Theory). The conclusion of the theoretical analysis is agreeable with the experimental results. So these results indicate that PTS combining theoretical calculation can be used as a new, indirect way to judge the composition of the clusters which are easy to be dissociated and difficult to be detected by mass spectroscopy. |
| 语种 | 英语 |
| WOS记录号 | WOS:000248547100005 |
| 出版者 | OLDENBOURG VERLAG |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60551]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhu, Qihe |
| 作者单位 | Chinese Acad Sci, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bi, Weibin,Xu, Xiling,Huang, Jiangou,et al. Study on the (HI)(m)(H(2)O)(n) clusters by photofragment translational spectroscopy and ab-initio calculation[J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS,2007,221(6):815-824. |
| APA | Bi, Weibin,Xu, Xiling,Huang, Jiangou,Xiao, Daoqing,Tang, Zichao,&Zhu, Qihe.(2007).Study on the (HI)(m)(H(2)O)(n) clusters by photofragment translational spectroscopy and ab-initio calculation.ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS,221(6),815-824. |
| MLA | Bi, Weibin,et al."Study on the (HI)(m)(H(2)O)(n) clusters by photofragment translational spectroscopy and ab-initio calculation".ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS 221.6(2007):815-824. |
入库方式： OAI收割
来源：化学研究所
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