中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Two new scorpionates vanadium haloperoxidases model compexes: Syntesis and structure of VO(O-2)(pzH)(HB(pz)(3)) amd VO(O-2)(pzH)(B(pz)(4)) (pzH = pyrazole(C3H4N2))

文献类型:期刊论文

作者Xing, Yongheng; Zhang, Yuanhong; Sun, Zheng; Ye, Ling; Xu, Yongting; Ge, Maofa; Zhang, Baoli; Niu, Shuyun
刊名JOURNAL OF INORGANIC BIOCHEMISTRY
出版日期2007
卷号101期号:1页码:36-43
关键词Peroxovanadium(v) Complexes Haloperoxidases Poly(1h-pyrazol-l-yl)Borate Crystal Structure
ISSN号0162-0134
DOI10.1016/j.jinorgbio.2006.07.018
英文摘要Using vanadate, poly(1H-pyrazol-1-yl)borate and pyrazole as starting materials, two new neutral peroxovanadium(V) complexes with poly(1H-pyrazol-1-yl)borate, VO(O-2)(pzH)(HB(pz)(3))(1) and VO(O-2)(pzH)(B(pz)(4))(2), were synthesized successfully. Both complexes were characterized by elemental analysis, IR, UV-vis and NMR spectra. And the structure of complex 1 was determined by X-ray diffraction, which is somewhat relevant for haloperoxidase enzymes. Cytotoxic effects also are discussed on 3T3 cell proliferation. In the concentration range (0.1-100 mu mol), both complexes have an inhibiting cellular proliferation effect. When the cells cultivated with the complexes at high dose, the toxicity effect of both complexes is more and more predominant. (c) 2006 Elsevier Inc. All rights reserved.
语种英语
WOS记录号WOS:000243458400006
出版者ELSEVIER SCIENCE INC
源URL[http://ir.iccas.ac.cn/handle/121111/60573]  
专题中国科学院化学研究所
通讯作者Xing, Yongheng
作者单位1.Liaoning Normal Univ, Bioinorgan Lab, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
3.Liaoning Normal Univ, Expt Ctr, Dalian 116029, Peoples R China
4.Jilin Univ, Supramol Lab, Changchun 130023, Peoples R China
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Xing, Yongheng,Zhang, Yuanhong,Sun, Zheng,et al. Two new scorpionates vanadium haloperoxidases model compexes: Syntesis and structure of VO(O-2)(pzH)(HB(pz)(3)) amd VO(O-2)(pzH)(B(pz)(4)) (pzH = pyrazole(C3H4N2))[J]. JOURNAL OF INORGANIC BIOCHEMISTRY,2007,101(1):36-43.
APA Xing, Yongheng.,Zhang, Yuanhong.,Sun, Zheng.,Ye, Ling.,Xu, Yongting.,...&Niu, Shuyun.(2007).Two new scorpionates vanadium haloperoxidases model compexes: Syntesis and structure of VO(O-2)(pzH)(HB(pz)(3)) amd VO(O-2)(pzH)(B(pz)(4)) (pzH = pyrazole(C3H4N2)).JOURNAL OF INORGANIC BIOCHEMISTRY,101(1),36-43.
MLA Xing, Yongheng,et al."Two new scorpionates vanadium haloperoxidases model compexes: Syntesis and structure of VO(O-2)(pzH)(HB(pz)(3)) amd VO(O-2)(pzH)(B(pz)(4)) (pzH = pyrazole(C3H4N2))".JOURNAL OF INORGANIC BIOCHEMISTRY 101.1(2007):36-43.

入库方式: OAI收割

来源:化学研究所

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