Syntheses and structural characterization of a series of one-dimensional fluorotitanophosphates (NH4)(x)K4-x[Ti2PO4F9] (x=0, 0.70, 1.00, 1.25)
文献类型：期刊论文
| 作者 | Yang, Sihai1; Li, Guobao1; Li, Lei1; Tian, Shujian1; Liao, Fuhui1; Xiong, Ming2; Lin, Jianhua1 |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2007-12-24 |
| 卷号 | 46期号:26页码:11431-11436 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/ic701715k |
| 英文摘要 | A series of novel fluorotitanophosphates with a general formula (NH4)(x)K4-x[Ti2PO4F9] (x = 0, 0.70, 1.00, 1.25), named as 1, 2, 3, and 4 respectively) have been synthesized under hydrothermal conditions. Their structures were determined by X-ray single-crystal diffraction technique, which show that all of the phases in this series contain an idental anionic fluorotitanophosphate chain, consisting of alternating linkage of PO4 tetrahedra and TiO2F4 octahedra. The fluorotitanophosphate chain is unique, which is different from the first titanophosphate chain found in [Ti3P6O27]center dot 5[NH3CH2-CH2NH3]center dot 2H3O. Another interesting observation of this series is that, by partial substitution of potassium by ammonium, the structure converts to a more-symmetric version, while maintaining all of the topological feature. |
| 语种 | 英语 |
| WOS记录号 | WOS:000251773700058 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60613]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Guobao |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 2.China Univ Geosci, X Ray Lab, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Sihai,Li, Guobao,Li, Lei,et al. Syntheses and structural characterization of a series of one-dimensional fluorotitanophosphates (NH4)(x)K4-x[Ti2PO4F9] (x=0, 0.70, 1.00, 1.25)[J]. INORGANIC CHEMISTRY,2007,46(26):11431-11436. |
| APA | Yang, Sihai.,Li, Guobao.,Li, Lei.,Tian, Shujian.,Liao, Fuhui.,...&Lin, Jianhua.(2007).Syntheses and structural characterization of a series of one-dimensional fluorotitanophosphates (NH4)(x)K4-x[Ti2PO4F9] (x=0, 0.70, 1.00, 1.25).INORGANIC CHEMISTRY,46(26),11431-11436. |
| MLA | Yang, Sihai,et al."Syntheses and structural characterization of a series of one-dimensional fluorotitanophosphates (NH4)(x)K4-x[Ti2PO4F9] (x=0, 0.70, 1.00, 1.25)".INORGANIC CHEMISTRY 46.26(2007):11431-11436. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。