Synthesis of ABC-type miktoarm star polymers by "click" chemistry, ATRP and ROP
文献类型：期刊论文
| 作者 | Deng, Guohua; Ma, Deyun; Xu, Zizhen |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2007-04-01 |
| 卷号 | 43期号:4页码:1179-1187 |
| 关键词 | "click" Reaction Abc-type Miktoarm Star Polymer Ring-opening Polymerization Atom Transfer Radical Polymerization |
| ISSN号 | 0014-3057 |
| DOI | 10.1016/j.eurpolymj.2007.01.034 |
| 英文摘要 | ABC-type miktoarm star polymers, poly(ethylene oxide)-block-polystyrene-block-poly (epsilon-caprolactone)s (PEO-b-PS-bPCL) were synthesized via combination of "click" chemistry, atom-transfer radical polymerization (ATRP) and ring opening polymerization (ROP). Azide ended PEO arms, PEO-N-3, and a trifunctional molecule, propargyl 2-hydroxylmethyl-2-(alpha-bromoisobutyraloxymethyl)-propionate (PHBP), were prepared first, respectively. A "click" reaction of PEO-N-3 and PHBP generated a PEO inacroinitiator, PEO-(Br)(OH) with two functionalities, one is hydroxyl group and the other is (alpha-bromoisobutyraloxyl group. Consecutive ATRP of styrene (St) and ROP epsilon-caprolactone (epsilon-CL) from the PEO macroinitiator produced the PEO-b-PS-b-PCL miktoarm stars. All the structures of the polymers were determined. (C) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000246347900009 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60623]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Deng, Guohua |
| 作者单位 | 1.S China Univ Technol, Coll Chem, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, Guohua,Ma, Deyun,Xu, Zizhen. Synthesis of ABC-type miktoarm star polymers by "click" chemistry, ATRP and ROP[J]. EUROPEAN POLYMER JOURNAL,2007,43(4):1179-1187. |
| APA | Deng, Guohua,Ma, Deyun,&Xu, Zizhen.(2007).Synthesis of ABC-type miktoarm star polymers by "click" chemistry, ATRP and ROP.EUROPEAN POLYMER JOURNAL,43(4),1179-1187. |
| MLA | Deng, Guohua,et al."Synthesis of ABC-type miktoarm star polymers by "click" chemistry, ATRP and ROP".EUROPEAN POLYMER JOURNAL 43.4(2007):1179-1187. |
入库方式： OAI收割
来源：化学研究所
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