A unique 3-D 3d-4f heterometallic coordination polymer with double betaine ligand: Crystal structure and magnetic properties
文献类型：期刊论文
| 作者 | Li, Yan; Zheng, Fa-Kun; Zou, Jian-Ping; Zou, Wen-Qiang; Ma, Hong-Wei; Guo, Guo-Cong; Lu, Can-Zhong; Huang, Jin-Shun |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2007-07-01 |
| 卷号 | 10期号:7页码:787-791 |
| 关键词 | Coordination Polymer Carboxylate Ligands Heterometallic Complexes Magnetic Properties |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2007.03.027 |
| 英文摘要 | A unique 3d-4f heterometallic coordination polymer with double betaine ligand, [GdCu2(L-1)(4)(H2O2)(2)](ClO4)(7) center dot 6H(2)O 1 (L-1 = 1,3-bis(pyridinio-4-carboxylato)-propane), has been synthesized by the self-assembly of Cu(ClO4)(2) and Gd(ClO4)(3) with flexible double betaine ligand L-1, and structurally characterized by single-crystal X-ray diffraction. The structure of 1 can be regarded as being constructed by the cross-linkage of the vertex-sharing double-paddle-wheel-like trinuclear [Cu(COO)(4)Gd(COO)(4)Cu] units and L-1 ligands to produce an interesting cationic NaCl-like framework with a 4(12)6(3) topology, which is counter-balanced by the perchlorate ions located in the interspaces of the framework. Variable-temperature magnetic susceptibilities of 1 show there is no magnetic interaction between the Cu(II) and Gd(III) ions. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000247795000013 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60723]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zheng, Fa-Kun |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yan,Zheng, Fa-Kun,Zou, Jian-Ping,et al. A unique 3-D 3d-4f heterometallic coordination polymer with double betaine ligand: Crystal structure and magnetic properties[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2007,10(7):787-791. |
| APA | Li, Yan.,Zheng, Fa-Kun.,Zou, Jian-Ping.,Zou, Wen-Qiang.,Ma, Hong-Wei.,...&Huang, Jin-Shun.(2007).A unique 3-D 3d-4f heterometallic coordination polymer with double betaine ligand: Crystal structure and magnetic properties.INORGANIC CHEMISTRY COMMUNICATIONS,10(7),787-791. |
| MLA | Li, Yan,et al."A unique 3-D 3d-4f heterometallic coordination polymer with double betaine ligand: Crystal structure and magnetic properties".INORGANIC CHEMISTRY COMMUNICATIONS 10.7(2007):787-791. |
入库方式： OAI收割
来源：化学研究所
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