Synthesis, structure and catalytic properties of a novel zirconium guanidinato complex [Zr{ArNC(NMe2)N(SiMe3)} (mu(2)-Cl)Cl-2](2)[Ar=2, 6-Pr-i(2)-C6H3]
文献类型：期刊论文
| 作者 | Zhou, Meisu; Zhang, Shu; Tong, Hongbo; Sun, Wen-Hua ; Liu, Diansheng
|
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2007-11-01 |
| 卷号 | 10期号:11页码:1262-1264 |
| 关键词 | Zirconium Complex Guanidinate Catalysis Ethylene Polymerization |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2007.08.001 |
| 英文摘要 | A novel non-symmetric zirconium guanidinato complex, [(Zr{ArNC(NMe2)N(SiMe3)}(mu(2)-Cl)Cl-2}(2)] (Ar = 2.6-Pr-i(2)-C6H3). was synthesized and structurally characterized. Catalytic studies showed that the zirconium complex was active for ethylene polymerization with the activity of 4.98 x 10(5) g PE/mol Zr h. The influences of cocatalysts, Al/Zr molar ratios and ethylene pressures on the activities were investigated. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000251522700006 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60731]  |
| 专题 | 中国科学院化学研究所 化学研究所_工程塑料实验室 |
| 通讯作者 | Zhou, Meisu |
| 作者单位 | 1.Shanxi Univ, Inst Appl Chem, Taiyuan 030006, Peoples R China 2.Chinese Acad Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Meisu,Zhang, Shu,Tong, Hongbo,et al. Synthesis, structure and catalytic properties of a novel zirconium guanidinato complex [Zr{ArNC(NMe2)N(SiMe3)} (mu(2)-Cl)Cl-2](2)[Ar=2, 6-Pr-i(2)-C6H3][J]. INORGANIC CHEMISTRY COMMUNICATIONS,2007,10(11):1262-1264. |
| APA | Zhou, Meisu,Zhang, Shu,Tong, Hongbo,Sun, Wen-Hua,&Liu, Diansheng.(2007).Synthesis, structure and catalytic properties of a novel zirconium guanidinato complex [Zr{ArNC(NMe2)N(SiMe3)} (mu(2)-Cl)Cl-2](2)[Ar=2, 6-Pr-i(2)-C6H3].INORGANIC CHEMISTRY COMMUNICATIONS,10(11),1262-1264. |
| MLA | Zhou, Meisu,et al."Synthesis, structure and catalytic properties of a novel zirconium guanidinato complex [Zr{ArNC(NMe2)N(SiMe3)} (mu(2)-Cl)Cl-2](2)[Ar=2, 6-Pr-i(2)-C6H3]".INORGANIC CHEMISTRY COMMUNICATIONS 10.11(2007):1262-1264. |
入库方式： OAI收割
来源：化学研究所
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