中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Shape-memory and biocompatibility properties of segmented polyurethanes based on poly(L-lactide)

文献类型:期刊论文

作者Ping Peng; Wang Wen-Shou; Zhang Pei-Biao; Chen Xue-Si; Jing Xia-Bin
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
出版日期2007-02-10
卷号28期号:2页码:371-375
关键词Polyurethane Poly(L-lactide) Shape Memory Biocompatibility
ISSN号0251-0790
英文摘要A series of segmented poly (L-lactide)-polyurethanes (PLA-PU) were synthesized by a two-step method, with oligo-poly(L-lactide) (PLA) as the soft segments and the reaction product of 2,4-toluene diisocyanate(TDI) and ethylene glycol(EG) as the hard segments. The shape memory properties of PLA-PUs were examined. The processed PLA-PUs could recover almost 100% to their original shape within 10 degrees C from the lowest recovery temperature. In the recovery process, the PLA-PUs showed a maximum contracting stress of shape change in the range of 1.5-4 MPa depending on the PLA segmental length and the hard-segmental content and higher than that of poly (e-caprolactone polyurethane) (PCL-PU). Besides, the influence of deforming and fixing temperatures on shape memory properties of PLA-PU was studied in detail. They could affect not only the recovery temperature but also the maximum contracting stress. The experiments of cell incubation were used to evaluate the biocompatibility of PLA-PU. The results show that the biocompatibility of PLA-PU is comparable to that of the pure PLA. This kind of polyurethane can be used as implanted medical devices with a shape memory property.
语种英语
WOS记录号WOS:000244413000043
出版者HIGHER EDUCATION PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/60795]  
专题中国科学院化学研究所
通讯作者Jing Xia-Bin
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Ping Peng,Wang Wen-Shou,Zhang Pei-Biao,et al. Shape-memory and biocompatibility properties of segmented polyurethanes based on poly(L-lactide)[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2007,28(2):371-375.
APA Ping Peng,Wang Wen-Shou,Zhang Pei-Biao,Chen Xue-Si,&Jing Xia-Bin.(2007).Shape-memory and biocompatibility properties of segmented polyurethanes based on poly(L-lactide).CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,28(2),371-375.
MLA Ping Peng,et al."Shape-memory and biocompatibility properties of segmented polyurethanes based on poly(L-lactide)".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 28.2(2007):371-375.

入库方式: OAI收割

来源:化学研究所

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