2-arylimino-9-phenyl-1,10-phenanthrolinyl-iron, -cobalt and -nickel complexes: Synthesis, characterization and ethylene oligomerization behavior
文献类型：期刊论文
| 作者 | Jie, Suyun1,2; Zhang, Shu1,2; Sun, Wen-Hua1,2
|
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2007-12-01 |
| 期号 | 35页码:5584-5598 |
| 关键词 | Nitrogen Ligands Late Transition Metals Iron Ethylene Oligomerization |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.200700690 |
| 英文摘要 | A series of 2-imino-9-phenyl-1,10-phenanthrolines 1-6 has been prepared and investigated as new tridentate N3 ligands in coordination with metal chlorides. Their iron(II) (1a-6a), cobalt(II) (1b-6b), and nickel(II) (1c-6c) complexes have been synthesized and characterized by elemental and spectroscopic analysis in conjunction with single-crystal X-ray diffraction studies. Some of the iron complexes show good activities in the selective dimerization of ethylene upon treatment with MAO or MMAO, while the cobalt complexes show higher activities than their iron analogues and lead to the formation of C-6 and C-8 oligomers. The nickel complexes display high catalytic activities toward ethylene oligomerization in the presence of Et2AlCl and an auxiliary ligand (PPh3). ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007). |
| 语种 | 英语 |
| WOS记录号 | WOS:000252112600015 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60803]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jie, Suyun,Zhang, Shu,Sun, Wen-Hua. 2-arylimino-9-phenyl-1,10-phenanthrolinyl-iron, -cobalt and -nickel complexes: Synthesis, characterization and ethylene oligomerization behavior[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2007(35):5584-5598. |
| APA | Jie, Suyun,Zhang, Shu,&Sun, Wen-Hua.(2007).2-arylimino-9-phenyl-1,10-phenanthrolinyl-iron, -cobalt and -nickel complexes: Synthesis, characterization and ethylene oligomerization behavior.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(35),5584-5598. |
| MLA | Jie, Suyun,et al."2-arylimino-9-phenyl-1,10-phenanthrolinyl-iron, -cobalt and -nickel complexes: Synthesis, characterization and ethylene oligomerization behavior".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .35(2007):5584-5598. |
入库方式： OAI收割
来源：化学研究所
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