Synthesis and self-assembly of brush-rod diblock copolymers in the mixed solvent of TBT/H2O
文献类型：期刊论文
| 作者 | Cao, Hongqing; Lin, Weiran; Liu, Anhua; Zhang, Jie; Wan, Xinhua; Zhou, Qifeng |
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2007-09-18 |
| 卷号 | 28期号:18-19页码:1883-1888 |
| ISSN号 | 1022-1336 |
| DOI | 10.1002/marc.200700241 |
| 英文摘要 | Two amphiphilic brush-rod block copolymers, PEGMA(37)-b-MBPS87 and PEGMA(37)-b-MBPS141., were synthesized via ATRP of poly(ethylene glycol) monomethyl ether methacrylate (PEGMA) and (+) -2, 5 -bis [4'-((S)-2-methylbutoxy)phenyl] styrene (MBPS). The self-assembly of the copolymers in THF/H2O was induced by different methods. Spheres were dominant morphologies of PEGMA(37)-b-MBPS87 regardless of the initial concentration and the rate of water addition. Increase of the length of hydrophobic block, as in PEGMA(37)-b- MBPS141, led to the coexistence of primary spheres, large compound spherical and rod-like micelles at a slow water addition rate. Injecting water into the THF solution of PEGAAA(37)-b- MBPS141 quickly or pouring the THF solution into large amount of water resulted only in the formation of spheres. |
| 语种 | 英语 |
| WOS记录号 | WOS:000249899400004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60853]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, Xinhua |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, Minist Educ, Beijing Natl Lab Mol Sci,Key Lab Polymer Chem & P, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Hongqing,Lin, Weiran,Liu, Anhua,et al. Synthesis and self-assembly of brush-rod diblock copolymers in the mixed solvent of TBT/H2O[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2007,28(18-19):1883-1888. |
| APA | Cao, Hongqing,Lin, Weiran,Liu, Anhua,Zhang, Jie,Wan, Xinhua,&Zhou, Qifeng.(2007).Synthesis and self-assembly of brush-rod diblock copolymers in the mixed solvent of TBT/H2O.MACROMOLECULAR RAPID COMMUNICATIONS,28(18-19),1883-1888. |
| MLA | Cao, Hongqing,et al."Synthesis and self-assembly of brush-rod diblock copolymers in the mixed solvent of TBT/H2O".MACROMOLECULAR RAPID COMMUNICATIONS 28.18-19(2007):1883-1888. |
入库方式： OAI收割
来源：化学研究所
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