中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Diastereoselectivity in the Staudinger reaction: a useful probe for investigation of nonthermal microwave effects

文献类型:期刊论文

作者Hu, Libo; Wang, Yikai; Li, Bonan; Du, Da-Ming; Xu, Jiaxi
刊名TETRAHEDRON
出版日期2007-09-17
卷号63期号:38页码:9387-9392
关键词Diastereoselectivity Imine Ketene Beta-lactam Microwave Nonthermal Effect Staudinger Reaction Stereoselectivity Temperature
ISSN号0040-4020
DOI10.1016/j.tet.2007.06.112
英文摘要The effect of microwave irradiation on the selectivity, especially stereoselectivity, is one of the most important issues in microwave-assisted organic reactions. The diastereoselectivity in Staudinger reactions involving the representative ketenes and the corresponding matched imines has been used as a probe to investigate carefully the existence of the specific nonthermal microwave effects. The results indicate that the microwave irradiation-controlled stereoselectivity in the Staudinger reaction is in fact the contribution of temperature. No specific nonthermal microwave effect was found in the Staudinger reaction. (C) 2007 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000252091900010
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/60875]  
专题中国科学院化学研究所
通讯作者Xu, Jiaxi
作者单位Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Hu, Libo,Wang, Yikai,Li, Bonan,et al. Diastereoselectivity in the Staudinger reaction: a useful probe for investigation of nonthermal microwave effects[J]. TETRAHEDRON,2007,63(38):9387-9392.
APA Hu, Libo,Wang, Yikai,Li, Bonan,Du, Da-Ming,&Xu, Jiaxi.(2007).Diastereoselectivity in the Staudinger reaction: a useful probe for investigation of nonthermal microwave effects.TETRAHEDRON,63(38),9387-9392.
MLA Hu, Libo,et al."Diastereoselectivity in the Staudinger reaction: a useful probe for investigation of nonthermal microwave effects".TETRAHEDRON 63.38(2007):9387-9392.

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来源:化学研究所

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