Diastereoselectivity in the Staudinger reaction: a useful probe for investigation of nonthermal microwave effects
文献类型:期刊论文
| 作者 | Hu, Libo; Wang, Yikai; Li, Bonan; Du, Da-Ming; Xu, Jiaxi |
| 刊名 | TETRAHEDRON
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| 出版日期 | 2007-09-17 |
| 卷号 | 63期号:38页码:9387-9392 |
| 关键词 | Diastereoselectivity Imine Ketene Beta-lactam Microwave Nonthermal Effect Staudinger Reaction Stereoselectivity Temperature |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2007.06.112 |
| 英文摘要 | The effect of microwave irradiation on the selectivity, especially stereoselectivity, is one of the most important issues in microwave-assisted organic reactions. The diastereoselectivity in Staudinger reactions involving the representative ketenes and the corresponding matched imines has been used as a probe to investigate carefully the existence of the specific nonthermal microwave effects. The results indicate that the microwave irradiation-controlled stereoselectivity in the Staudinger reaction is in fact the contribution of temperature. No specific nonthermal microwave effect was found in the Staudinger reaction. (C) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000252091900010 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60875] ![]() |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xu, Jiaxi |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Libo,Wang, Yikai,Li, Bonan,et al. Diastereoselectivity in the Staudinger reaction: a useful probe for investigation of nonthermal microwave effects[J]. TETRAHEDRON,2007,63(38):9387-9392. |
| APA | Hu, Libo,Wang, Yikai,Li, Bonan,Du, Da-Ming,&Xu, Jiaxi.(2007).Diastereoselectivity in the Staudinger reaction: a useful probe for investigation of nonthermal microwave effects.TETRAHEDRON,63(38),9387-9392. |
| MLA | Hu, Libo,et al."Diastereoselectivity in the Staudinger reaction: a useful probe for investigation of nonthermal microwave effects".TETRAHEDRON 63.38(2007):9387-9392. |
入库方式: OAI收割
来源:化学研究所
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