中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Formation of the intermediate nitronyl nitroxide-anthracene dyad sensing saccharides

文献类型:期刊论文

作者Yu, Yanxin; Zhang, Deqing; Tan, Wei; Wang, Zhiyong; Zhu, Daoben
刊名BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
出版日期2007
卷号17期号:1页码:94-96
关键词Saccharides Sensor Nitronyl Nitroxide Anthracene Boronic Acid Fluorescence.
ISSN号0960-894X
DOI10.1016/j.bmcl.2006.09.081
英文摘要We design a new saccharides sensor based on the ensemble of compound 2 with a boronic group and compound 3 with two phenolic -OH groups, taking advantage of the fluorescence quenching ability of nitronyl nitroxides and reversible boronate formation between boronic acid and diol. The results show that the fluorescence of compound 2 was largely quenched upon addition of compound 3 due to the formation of the intermediate nitronyl nitroxide-anthracene dyad 1. Sequential addition of saccharides such as fructose to the ensemble of compounds 2 and 3 together with dyad 1 induced the fluorescence enhancement. These results clearly demonstrate the possibility to employ the ensemble of compounds 2 and 3 (with dyad 1) to sense saccharides. (c) 2006 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000243630500016
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/60885]  
专题中国科学院化学研究所
通讯作者Zhang, Deqing
作者单位1.Chinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
3.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
推荐引用方式
GB/T 7714
Yu, Yanxin,Zhang, Deqing,Tan, Wei,et al. Formation of the intermediate nitronyl nitroxide-anthracene dyad sensing saccharides[J]. BIOORGANIC & MEDICINAL CHEMISTRY LETTERS,2007,17(1):94-96.
APA Yu, Yanxin,Zhang, Deqing,Tan, Wei,Wang, Zhiyong,&Zhu, Daoben.(2007).Formation of the intermediate nitronyl nitroxide-anthracene dyad sensing saccharides.BIOORGANIC & MEDICINAL CHEMISTRY LETTERS,17(1),94-96.
MLA Yu, Yanxin,et al."Formation of the intermediate nitronyl nitroxide-anthracene dyad sensing saccharides".BIOORGANIC & MEDICINAL CHEMISTRY LETTERS 17.1(2007):94-96.

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来源:化学研究所

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