Investigation on Ru(II)-catalyzed reaction of [2,3]-sigmatropic rearrangement of sulfur ylide generated from metal carbene
文献类型：期刊论文
| 作者 | Xiao Qing; Wang Jian-Bo |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2007-08-28 |
| 卷号 | 65期号:16页码:1733-1735 |
| 关键词 | Ruthenium(Ii) Catalyst Alpha-diazo Carbonyl Compound [2 3]-sigmatropic Rearrangement Of Sulfonium Ylide |
| ISSN号 | 0567-7351 |
| 英文摘要 | The Doyle-Kirmse reaction, namely the [2,3]-sigmatropic rearrangement of sulfonium ylides generated from a-diazo carbonyl compounds and sulfides has been for the first time catalyzed by [RuCl2(p-cymene)](2). The reaction with allyl sulfides afforded the corresponding [2,3]-sigmatropic rearrangement products in moderate to good yields. The reaction with propargyl sulfide gave a mixture of allenic sulfide and furan. The former is the [2,3]-sigmatropic rearrangement product, while the latter is derived from the further rearrangement of the allene product under Ru(II) catalysis. |
| 语种 | 英语 |
| WOS记录号 | WOS:000249347100036 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60933]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xiao Qing |
| 作者单位 | 1.Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao Qing,Wang Jian-Bo. Investigation on Ru(II)-catalyzed reaction of [2,3]-sigmatropic rearrangement of sulfur ylide generated from metal carbene[J]. ACTA CHIMICA SINICA,2007,65(16):1733-1735. |
| APA | Xiao Qing,&Wang Jian-Bo.(2007).Investigation on Ru(II)-catalyzed reaction of [2,3]-sigmatropic rearrangement of sulfur ylide generated from metal carbene.ACTA CHIMICA SINICA,65(16),1733-1735. |
| MLA | Xiao Qing,et al."Investigation on Ru(II)-catalyzed reaction of [2,3]-sigmatropic rearrangement of sulfur ylide generated from metal carbene".ACTA CHIMICA SINICA 65.16(2007):1733-1735. |
入库方式： OAI收割
来源：化学研究所
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