中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains

文献类型:期刊论文

作者Zhang, Yanhong; Xu, Zizhen; Li, Xiaokai; Chen, Yongming
刊名JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
出版日期2007-08-01
卷号45期号:15页码:3303-3310
关键词Dendrimers Dendronized Polymers Graft Copolymers Amphiphiles Metal-polymer Complexes
ISSN号0887-624X
DOI10.1002/pola.22080
英文摘要A new kind of dendronized polymer brush with metallo-supramolecular polymer side chains was fabricated by a combination of macromonomer and graft-to approach. The alternating copolymers of maleic anhydride and styryl macromonomers pendant with Frechet-type dendrons of three generations were reported previously. In this article, terpyridine groups were introduced along the backbone of the dendronized polymers through the amidolysis of anhydride groups. The terpyridine functionalized. PEO linear chains were then incorporated through the complexation of terpyridine and Ru(II) ion. Thus, dendronized polymer brushes with amphiphilic properties were synthesized. AFM analysis showed worm-like single molecular morphologies of the polymers of three generations, and H-1 NMR analysis indicated that such molecular brushes had an amphiphilic nature in solution. (C) 2007 Wiley Periodicals, Inc.
语种英语
WOS记录号WOS:000248021700014
出版者JOHN WILEY & SONS INC
源URL[http://ir.iccas.ac.cn/handle/121111/60939]  
专题中国科学院化学研究所
通讯作者Chen, Yongming
作者单位Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Yanhong,Xu, Zizhen,Li, Xiaokai,et al. Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2007,45(15):3303-3310.
APA Zhang, Yanhong,Xu, Zizhen,Li, Xiaokai,&Chen, Yongming.(2007).Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,45(15),3303-3310.
MLA Zhang, Yanhong,et al."Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 45.15(2007):3303-3310.

入库方式: OAI收割

来源:化学研究所

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