Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains
文献类型:期刊论文
作者 | Zhang, Yanhong; Xu, Zizhen; Li, Xiaokai; Chen, Yongming |
刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
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出版日期 | 2007-08-01 |
卷号 | 45期号:15页码:3303-3310 |
关键词 | Dendrimers Dendronized Polymers Graft Copolymers Amphiphiles Metal-polymer Complexes |
ISSN号 | 0887-624X |
DOI | 10.1002/pola.22080 |
英文摘要 | A new kind of dendronized polymer brush with metallo-supramolecular polymer side chains was fabricated by a combination of macromonomer and graft-to approach. The alternating copolymers of maleic anhydride and styryl macromonomers pendant with Frechet-type dendrons of three generations were reported previously. In this article, terpyridine groups were introduced along the backbone of the dendronized polymers through the amidolysis of anhydride groups. The terpyridine functionalized. PEO linear chains were then incorporated through the complexation of terpyridine and Ru(II) ion. Thus, dendronized polymer brushes with amphiphilic properties were synthesized. AFM analysis showed worm-like single molecular morphologies of the polymers of three generations, and H-1 NMR analysis indicated that such molecular brushes had an amphiphilic nature in solution. (C) 2007 Wiley Periodicals, Inc. |
语种 | 英语 |
WOS记录号 | WOS:000248021700014 |
出版者 | JOHN WILEY & SONS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/60939] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, Yongming |
作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Yanhong,Xu, Zizhen,Li, Xiaokai,et al. Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2007,45(15):3303-3310. |
APA | Zhang, Yanhong,Xu, Zizhen,Li, Xiaokai,&Chen, Yongming.(2007).Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,45(15),3303-3310. |
MLA | Zhang, Yanhong,et al."Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 45.15(2007):3303-3310. |
入库方式: OAI收割
来源:化学研究所
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