Facile evolution of asymmetric organocatalysts in water assisted by surfactant Bronsted acids
文献类型：期刊论文
| 作者 | Luo, Sanzhong1; Xu, Hui1; Li, Jiuyuan1; Zhang, Long2,3; Mi, Xueling2,3; Zheng, Xiaoxi1; Cheng, Jin-Pei2,3 |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2007-11-12 |
| 卷号 | 63期号:46页码:11307-11314 |
| 关键词 | Aldol Michael Addition Chiral Amine Surfactant Bronsted Acids |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2007.08.096 |
| 英文摘要 | Simple mixing of chiral amines and surfactant Bronsted acids such as p-dodecyl benzenesulfonic acid (DBSA) leads to highly effective and selective organocatalysts in water. The in situ generated catalysts catalyze highly stereoselective desymmetrization of prochiral ketones via direct aldol reactions (up to >16:1 dr, > 99% ee) in water using micelle as reaction media. The current strategy was also applied in asymmetric Michael addition leading to a catalytic system with good activity and stereoselectivity. (C) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000252094300009 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/60949]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Luo, Sanzhong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Chem Biol, BNLMS, Beijing 100080, Peoples R China 2.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China 3.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Sanzhong,Xu, Hui,Li, Jiuyuan,et al. Facile evolution of asymmetric organocatalysts in water assisted by surfactant Bronsted acids[J]. TETRAHEDRON,2007,63(46):11307-11314. |
| APA | Luo, Sanzhong.,Xu, Hui.,Li, Jiuyuan.,Zhang, Long.,Mi, Xueling.,...&Cheng, Jin-Pei.(2007).Facile evolution of asymmetric organocatalysts in water assisted by surfactant Bronsted acids.TETRAHEDRON,63(46),11307-11314. |
| MLA | Luo, Sanzhong,et al."Facile evolution of asymmetric organocatalysts in water assisted by surfactant Bronsted acids".TETRAHEDRON 63.46(2007):11307-11314. |
入库方式： OAI收割
来源：化学研究所
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