Well-defined ladder polymers synthesized via supramolecular architecture and their applications
文献类型：期刊论文
| 作者 | Zhou Qilong; Yan Shouke; Xie Ping; Zhang Rongben |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2007-10-01 |
| 期号 | 10页码:918-930 |
| 关键词 | Supramolecular Chemistry Stepwise/coupling Polymerization Ladder-like Polymer Liquid Crystal Microstructure |
| ISSN号 | 1000-3304 |
| 英文摘要 | Controlling the microstructure during polymer synthesis is an important goal in contemporary research on polymer chemistry; it is also a subject of advanced interdisciplinary studies of polymer science, supramolecular and material science. Ladder-like polymer has attracted much attention in recent years because it, in theory I has better resistance to all kinds of degradation than the conventional polymer with single-chain. "Suprarmolecular architecture directed stepwise/coupling polymerization" (SCP), reviewed in this paper, is a polymerization method combining polymer chemistry with supramolecular chemistry. In SCP,supramolecular structure is formed at first by using weak interaction between molecules; then polymerization is conducted. Some ladder-like polymers with well-defined structure were synthesized by using SCP, including polysilsesquioxane with organo or oxygenic bridge and polyester. In other words, SCP realized the goal of controlling the microstructure with supramolecular weak interaction. In addition, this paper also discussed the applications of ladder polymers to advanced materials, such as the application in liquid crystals with ladder polymer backbone, tubular polymer based on ladder-like polymer used in entrapping the curing agent of epoxy, and quasi-sieve polymer which can be used in the preparation of NLO maerials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000250566100005 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61011]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang Rongben |
| 作者单位 | Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou Qilong,Yan Shouke,Xie Ping,et al. Well-defined ladder polymers synthesized via supramolecular architecture and their applications[J]. ACTA POLYMERICA SINICA,2007(10):918-930. |
| APA | Zhou Qilong,Yan Shouke,Xie Ping,&Zhang Rongben.(2007).Well-defined ladder polymers synthesized via supramolecular architecture and their applications.ACTA POLYMERICA SINICA(10),918-930. |
| MLA | Zhou Qilong,et al."Well-defined ladder polymers synthesized via supramolecular architecture and their applications".ACTA POLYMERICA SINICA .10(2007):918-930. |
入库方式： OAI收割
来源：化学研究所
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