中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
One-pot synthesis of polyimides via Ni-catalyzed coupling of bis(chlorophthalimide)s

文献类型:期刊论文

作者Shang, Zhenping; Gao, Changlu; Wang, Zhen; Ding, Mengxian; Gao, Lianxun
刊名EUROPEAN POLYMER JOURNAL
出版日期2007-05-01
卷号43期号:5页码:2135-2140
关键词Polyimides Nickel-catalyst Bis(Chlorophthalimide)s
ISSN号0014-3057
DOI10.1016/j.europolymj.2006.05.029
英文摘要A one-pot synthesis method for the preparation of polyimides containing biphenyl units was developed via nickel-catalyzed coupling reaction of bis(chlorophthalimide)s which were prepared from chloroplithalic anhydrides and diamines in xylene. The resulting polyimides had inherent viscosities of above 0.60dL g(-1). In the meantime, the copolymerizations from a mixture of three isomeric bis(chlorophthalimide)s gave the polymers with inherent viscosities of 0.36-0.55 gdL(-1). The solubility and film formability of the copolymers were better than those of homopolymers from bis(4-chlorophthalimide). The 10% weight loss of these polyimides was between 470 and 531 degrees C. (C) 2006 Published by Elsevier Ltd.
语种英语
WOS记录号WOS:000247040600056
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/61127]  
专题中国科学院化学研究所
通讯作者Gao, Lianxun
作者单位Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Shang, Zhenping,Gao, Changlu,Wang, Zhen,et al. One-pot synthesis of polyimides via Ni-catalyzed coupling of bis(chlorophthalimide)s[J]. EUROPEAN POLYMER JOURNAL,2007,43(5):2135-2140.
APA Shang, Zhenping,Gao, Changlu,Wang, Zhen,Ding, Mengxian,&Gao, Lianxun.(2007).One-pot synthesis of polyimides via Ni-catalyzed coupling of bis(chlorophthalimide)s.EUROPEAN POLYMER JOURNAL,43(5),2135-2140.
MLA Shang, Zhenping,et al."One-pot synthesis of polyimides via Ni-catalyzed coupling of bis(chlorophthalimide)s".EUROPEAN POLYMER JOURNAL 43.5(2007):2135-2140.

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来源:化学研究所

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