Ionic-liquid-like copolymer stabilized nanocatalysts in ionic liquids - I. Platinum catalyzed selective hydrogenation of o-chloronitrobenzene
文献类型：期刊论文
| 作者 | Xiao, Chao-xian; Wang, Han-zhi; Mu, Xin-dong; Kou, Yuan |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2007-08-15 |
| 卷号 | 250期号:1页码:25-32 |
| 关键词 | Platinum Nanoparticles Nanocluster Colloid Quasi-homogeneous Molten Salts Density Functional Theory Calculations Ostwald Ripening Recycle Deactivate |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2007.05.009 |
| 英文摘要 | An ionic-liquid-like copolymer was used to stabilize the platinum nanoclusters in ionic liquids. Catalytic performance was tested by the selective hydrogenation of o-chloronitrobenzene. Platinum catalysts Pt-I (5.1 nm) and Pt-II (1.7 nm) both exhibited excellent activity and selectivity for the reaction and were recycled with the activity and selectivity preserved. An unprecedented total turnover number (>25,900) was obtained on the Pt-II catalyst. Infrared spectroscopy, transmission electron microscopy, X-ray diffraction characterizations, and density functional theory calculations were used to study the catalysts. (c) 2007 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000249104000004 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61163]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Kou, Yuan |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, PKU Green Chem Ctr, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Chao-xian,Wang, Han-zhi,Mu, Xin-dong,et al. Ionic-liquid-like copolymer stabilized nanocatalysts in ionic liquids - I. Platinum catalyzed selective hydrogenation of o-chloronitrobenzene[J]. JOURNAL OF CATALYSIS,2007,250(1):25-32. |
| APA | Xiao, Chao-xian,Wang, Han-zhi,Mu, Xin-dong,&Kou, Yuan.(2007).Ionic-liquid-like copolymer stabilized nanocatalysts in ionic liquids - I. Platinum catalyzed selective hydrogenation of o-chloronitrobenzene.JOURNAL OF CATALYSIS,250(1),25-32. |
| MLA | Xiao, Chao-xian,et al."Ionic-liquid-like copolymer stabilized nanocatalysts in ionic liquids - I. Platinum catalyzed selective hydrogenation of o-chloronitrobenzene".JOURNAL OF CATALYSIS 250.1(2007):25-32. |
入库方式： OAI收割
来源：化学研究所
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