Synthesis and properties of novel soluble polyimides having a spirobisindane-linked dianhydride unit
文献类型：期刊论文
| 作者 | Zhang, Quanyuan; Chen, Guang; Zhang, Suobo |
| 刊名 | POLYMER
 |
| 出版日期 | 2007-04-05 |
| 卷号 | 48期号:8页码:2250-2256 |
| 关键词 | Organosoluble Polyimide Thermal Properties Transparency |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2007.02.061 |
| 英文摘要 | A new synthetic procedure was elaborated allowing the preparation of semiaromatic dianhydride. N-Methyl protected 4-chlorophthalic anhydride was nitrated with HNO3 to produce N-methyl-4-chloro-5-nitrophthalimide (1). The aromatic nucleophilic substitution reaction between 5,5',6,6'-tetrahydroxy-3,3,3',3'-tetramethyl-1,1-spirobisindane and 1 afforded spirobisindane-linked bis(N-methylphthalimide) (2), which was hydrolyzed and subsequently dehydrated to give the corresponding dianhydride (3). The latter was polymerized with five different aromatic diamines to afford a series of aromatic polyimides. The properties of polyimides such as inherent viscosity, solubility, UV transparency and thermal stability were investigated to illustrate the contribution of the introduction of spirobisindane groups into the polyimide backbone. The resulting polyimides were readily soluble in polar solvents such as chloroform, THF and N-methyl-2-pyrrolidone. The glass-transition temperatures of these polyimides were in the range of 254-292 degrees C. The tensile strength, elongation at break, and Young's modulus of the polyimide film were 68.8-106.6 MPa, 5.9-9.8%, 1.7-2.0 GPa, respectively. The polymer films were colorless and transparent with the absorption cutoff wavelength at 286-308 nm. (c) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000246330200009 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61167]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Suobo |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Quanyuan,Chen, Guang,Zhang, Suobo. Synthesis and properties of novel soluble polyimides having a spirobisindane-linked dianhydride unit[J]. POLYMER,2007,48(8):2250-2256. |
| APA | Zhang, Quanyuan,Chen, Guang,&Zhang, Suobo.(2007).Synthesis and properties of novel soluble polyimides having a spirobisindane-linked dianhydride unit.POLYMER,48(8),2250-2256. |
| MLA | Zhang, Quanyuan,et al."Synthesis and properties of novel soluble polyimides having a spirobisindane-linked dianhydride unit".POLYMER 48.8(2007):2250-2256. |
入库方式： OAI收割
来源：化学研究所
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