Amination of [60]fullerene by ammonia and by primary and secondary aliphatic amines - Preparation of amino [60]fullerene peroxides
文献类型：期刊论文
| 作者 | Hu, Xiangqing; Jiang, Zhongping; Jia, Zhenshan; Huang, Shaohua; Yang, Xiaobing; Li, Yuliang; Gan, Liangbing; Zhang, Shiwei; Zhu, Daoben |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2007 |
| 卷号 | 13期号:4页码:1129-1141 |
| 关键词 | Amines Fullerenes Peroxides Radicals Single-electron Transfer |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.200600932 |
| 英文摘要 | Ammonia and aliphatic amines react readily in the oxygen-rich regions of the C, symmetric fullerene peroxides C-60(O)(OOtBu)(4) (1) and C-60(OH)(Br)(OOtBu)(4) (2c). Michael addition-type hydroamination of the 1,4-diene moiety on the central skew-pentagon was observed when I was treated with ammonia or with nonbulky primary amines, while sterically demanding primary amines opened the epoxy moiety to form vicinal aminohydroxy fullerene compounds with the amino group on the central pentagon. In 2c the bromo group was replaced under similar conditions by ammonia and primary amines. Cyclic secondary amines showed different reaction patterns, forming hydrogenation products or aminoketal-fullerenes when treated with 1 and 2c, respectively. Single-electron transfer (SET) is the key step in all the proposed mechanisms. The compounds were characterized by their spectroscopic data, and in addition, three single-crystal X-ray structures were obtained. |
| 语种 | 英语 |
| WOS记录号 | WOS:000243897700009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61173]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gan, Liangbing |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Peking Univ, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Xiangqing,Jiang, Zhongping,Jia, Zhenshan,et al. Amination of [60]fullerene by ammonia and by primary and secondary aliphatic amines - Preparation of amino [60]fullerene peroxides[J]. CHEMISTRY-A EUROPEAN JOURNAL,2007,13(4):1129-1141. |
| APA | Hu, Xiangqing.,Jiang, Zhongping.,Jia, Zhenshan.,Huang, Shaohua.,Yang, Xiaobing.,...&Zhu, Daoben.(2007).Amination of [60]fullerene by ammonia and by primary and secondary aliphatic amines - Preparation of amino [60]fullerene peroxides.CHEMISTRY-A EUROPEAN JOURNAL,13(4),1129-1141. |
| MLA | Hu, Xiangqing,et al."Amination of [60]fullerene by ammonia and by primary and secondary aliphatic amines - Preparation of amino [60]fullerene peroxides".CHEMISTRY-A EUROPEAN JOURNAL 13.4(2007):1129-1141. |
入库方式： OAI收割
来源：化学研究所
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