Confined intra-molecular clustering in orientated polyethylene after annealing
文献类型：期刊论文
| 作者 | Men, Yongfeng; Rieger, Jens; Lindner, Peter; Enderle, Hans-Friedrich; Lilge, Dieter; Kristen, Marc-Oliver; Mihan, Shahrarn; Jiang, Shichun |
| 刊名 | POLYMER
 |
| 出版日期 | 2007-04-24 |
| 卷号 | 48期号:9页码:2464-2469 |
| 关键词 | Sans Polyethylene Deformation |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2007.02.039 |
| 英文摘要 | Deuterated polyethylene tracer molecules with small amount of branches (12 C2H5- branches per 1000 backbone carbon atoms) were blended with a hydrogenated polyethylene matrix to form a homogenous mixture. The conformational evolution of the deuterated chains in a stretched semi-cry stall me film was observed via online small angle neutron scattering measurements during annealing at high temperatures close to the melting point. Because the sample was annealed at a temperature closely below its melting point, the crystalline lamellae were only partially molten and the system could not fully relax. The global chain dimensions were preserved during annealing. Recrystallization of released polymeric chain segments allows for local phase separation thus driving the deuterated chain segments into the confining interlamellar amorphous layers giving rise to an interesting intra-molecular clustering effect of the long deuterated chain. This clustering is deduced from characteristic small angle neutron scattering patterns. The confined phase separation has its origin in primarily the small amount of the branches on the deuterated polymers which impede the crystallization of the deuterated chain segments. (c) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000246329300002 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61269]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Men, Yongfeng |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.BASF AG, Polymer Phys, D-67056 Ludwigshafen, Germany 3.Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France 4.Basell Polyolefine GmbH, D-65926 Frankfurt, Germany 5.Univ Freiburg, Inst Phys, D-79104 Freiburg, Germany |
| 推荐引用方式 GB/T 7714 | Men, Yongfeng,Rieger, Jens,Lindner, Peter,et al. Confined intra-molecular clustering in orientated polyethylene after annealing[J]. POLYMER,2007,48(9):2464-2469. |
| APA | Men, Yongfeng.,Rieger, Jens.,Lindner, Peter.,Enderle, Hans-Friedrich.,Lilge, Dieter.,...&Jiang, Shichun.(2007).Confined intra-molecular clustering in orientated polyethylene after annealing.POLYMER,48(9),2464-2469. |
| MLA | Men, Yongfeng,et al."Confined intra-molecular clustering in orientated polyethylene after annealing".POLYMER 48.9(2007):2464-2469. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。