Experimental study of C2Cl3+NO2 reaction
文献类型：期刊论文
| 作者 | Xiang, Tian-Cheng; Liu, Kun-Hui; Su, Hong-Nnei |
| 刊名 | CHINESE JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2007-08-27 |
| 卷号 | 20期号:4页码:407-411 |
| 关键词 | Tr-ftir C2cl3 Vibrational Population Reaction Mechanism |
| ISSN号 | 1003-7713 |
| DOI | 10.1088/1674-0068/20/04/407-411 |
| 英文摘要 | The free radical reaction Of C2Cl3 with NO2 was investigated by step-scan time-resolved FTIR (TR-FTIR) emission spectroscopy. Due to the vibrationally excited products Of Cl2CO, NO, and CO, strong IR emission bands were observed with high resolution TR-FTIR spectra. Four reaction channels forming C2Cl3O+NO, CCl3CO+NO, CO+NO+CCl3, and ClCNO+Cl2CO were elucidated, respectively. Spectral fitting showed that the product CO was highly vibrationally excited with the nascent average vibrational energy of 60.2 kJ/mol. Possible reaction mechanism via intermediates C2Cl3NO2 and C2Cl3ONO was proposed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000249465100013 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61283]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Su, Hong-Nnei |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang, Tian-Cheng,Liu, Kun-Hui,Su, Hong-Nnei. Experimental study of C2Cl3+NO2 reaction[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2007,20(4):407-411. |
| APA | Xiang, Tian-Cheng,Liu, Kun-Hui,&Su, Hong-Nnei.(2007).Experimental study of C2Cl3+NO2 reaction.CHINESE JOURNAL OF CHEMICAL PHYSICS,20(4),407-411. |
| MLA | Xiang, Tian-Cheng,et al."Experimental study of C2Cl3+NO2 reaction".CHINESE JOURNAL OF CHEMICAL PHYSICS 20.4(2007):407-411. |
入库方式： OAI收割
来源：化学研究所
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