Insulin-like model complexes: Synthesis, spectra characterization and crystal structure of two novel oxovanadium complexes with poly(pyrazolyl)borate ligands VO(HB(pz)(3)(H2B(pz)(2)) and VO(B(pz)(4))(2)
文献类型：期刊论文
| 作者 | Xing, Yong-Heng; Zhang, Bao-Li; Zhang, Yuan-Hong; Yuan, Hou-Qun; Sun, Zheng; Ge, Mao-Fa |
| 刊名 | POLYHEDRON
 |
| 出版日期 | 2007-08-06 |
| 卷号 | 26期号:13页码:3037-3044 |
| 关键词 | Oxovanadium (Iv) Complexes Poly(Pyrazolyl)Borate Crystal Structure Quantum Chemistry Calculation |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/j.poly.2007.02.031 |
| 英文摘要 | Two new oxovanadium (IV) complexes VO(HB(pZ)(3),B(PZ)2) (1) and VO(B(PZ)4)2 (2) have been obtained by the reaction of oxovanadium sulfate with the corresponding ligands KHB(PZ)3, KH,B-2(pz)2 and KB(PZ)4, respectively. The two complexes were characterized by elemental analyses, IR, UV-Vis and X-ray diffraction. Complex I crystallizes in the orthorhombic space group, Pca2(1). Complex 2 crystallizes in the orthorhombic space group, Pna2(1). In both complexes, five nitrogen atoms and one oxygen atom coordinate to the vanadium atom, forming a distorted octahedral geometry (VON5). In addition, related spectra characterization, hydrogen-binding properties, structural configuration and quantum chemistry calculations are also discussed. (c) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000249001300017 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61345]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing, Yong-Heng |
| 作者单位 | 1.Liaoning Normal Univ, Bioinorgan Lab, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xing, Yong-Heng,Zhang, Bao-Li,Zhang, Yuan-Hong,et al. Insulin-like model complexes: Synthesis, spectra characterization and crystal structure of two novel oxovanadium complexes with poly(pyrazolyl)borate ligands VO(HB(pz)(3)(H2B(pz)(2)) and VO(B(pz)(4))(2)[J]. POLYHEDRON,2007,26(13):3037-3044. |
| APA | Xing, Yong-Heng,Zhang, Bao-Li,Zhang, Yuan-Hong,Yuan, Hou-Qun,Sun, Zheng,&Ge, Mao-Fa.(2007).Insulin-like model complexes: Synthesis, spectra characterization and crystal structure of two novel oxovanadium complexes with poly(pyrazolyl)borate ligands VO(HB(pz)(3)(H2B(pz)(2)) and VO(B(pz)(4))(2).POLYHEDRON,26(13),3037-3044. |
| MLA | Xing, Yong-Heng,et al."Insulin-like model complexes: Synthesis, spectra characterization and crystal structure of two novel oxovanadium complexes with poly(pyrazolyl)borate ligands VO(HB(pz)(3)(H2B(pz)(2)) and VO(B(pz)(4))(2)".POLYHEDRON 26.13(2007):3037-3044. |
入库方式： OAI收割
来源：化学研究所
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