Spectroscopic and theoretical studies on the photophysical Properties of dichlorotriazine derivatives
文献类型：期刊论文
| 作者 | Li, Man-Yu; Hao, Rui; Fu, Li-Min; Su, Wen-Jie; Zhao, Xiao-Hui; Zhang, Jian-Ping; Ai, Xi-Cheng; Sun, Meng-Tao; Wang, Yuan |
| 刊名 | CHEMICAL PHYSICS LETTERS
 |
| 出版日期 | 2007-08-27 |
| 卷号 | 444期号:4-6页码:297-303 |
| ISSN号 | 0009-2614 |
| DOI | 10.1016/j.cpiett.2007.07.027 |
| 英文摘要 | One- and two-photon photophysical properties of the cyanuric chloride derivatives, 2-(4'-N,N-diethylamino)phenyl-4,6-dichloro-1,3,5-triazine (PDT) and 2-(3',5'-dimethyl-4'-N,N-diethylamino)phenyl-4,6-dichloro-1,3,5-triazine (MPDT), were investigated. Compared to PDT, the methyl substitutes in MPDT caused drastic reduction in molar extinction coefficient, fluorescence quantum yield and two-photon absorption cross-section (delta(TPA)), and induced significant increase in Stokes shift. An optically forbidden but two-photon allowed S-2 state with prominent intra-molecular charge-transfer character is found to be responsible for the two-fold larger delta(TPA) of PDT (188 GM at 800 nm) than that of MPDT (94 GM at 780 nm). The methyl substitutes in MPDT considerably enhance the S-1-state contribution to its delta(TPA), while the steric hindrance does not significantly destroy the conjugation between the electron lone pair of N1 and the aromatic pi-electrons. (C) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000249600500017 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61383]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Jian-Ping |
| 作者单位 | 1.Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stabel Speci, BNLMS, Beijing 100080, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 4.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Man-Yu,Hao, Rui,Fu, Li-Min,et al. Spectroscopic and theoretical studies on the photophysical Properties of dichlorotriazine derivatives[J]. CHEMICAL PHYSICS LETTERS,2007,444(4-6):297-303. |
| APA | Li, Man-Yu.,Hao, Rui.,Fu, Li-Min.,Su, Wen-Jie.,Zhao, Xiao-Hui.,...&Wang, Yuan.(2007).Spectroscopic and theoretical studies on the photophysical Properties of dichlorotriazine derivatives.CHEMICAL PHYSICS LETTERS,444(4-6),297-303. |
| MLA | Li, Man-Yu,et al."Spectroscopic and theoretical studies on the photophysical Properties of dichlorotriazine derivatives".CHEMICAL PHYSICS LETTERS 444.4-6(2007):297-303. |
入库方式： OAI收割
来源：化学研究所
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