Polypropylene as a carbon source for the synthesis of multi-walled carbon nanotubes via catalytic combustion
文献类型：期刊论文
| 作者 | Jiang, Zhiwei; Song, Rongjun; Bi, Wuguo; Lu, Jun; Tang, Tao |
| 刊名 | CARBON
 |
| 出版日期 | 2007-02-01 |
| 卷号 | 45期号:2页码:449-458 |
| ISSN号 | 0008-6223 |
| DOI | 10.1016/j.carbon.2006.08.012 |
| 英文摘要 | Multi-walled carbon nanotubes (MWCNTs) were efficiently synthesized by catalytic combustion of polypropylene (PP) using nickel compounds (such as Ni2O3, NiO, Ni(OH)(2) and NiCO3 (.) 2Ni(OH)(2)) as catalysts in the presence of organic-modified montmorillonite (OMMT) at 630-830 degrees C. Morphologies of the sample undergoing different combustion times were observed to investigate actual process producing MWCNTs by this method. The obtained MWCNTs were characterized by X-ray diffraction (XRD), transmission electron microscope and Raman spectroscopy. The yield of MWCNTs was affected by the composition of PP mixtures with OMMT and nickel compounds and the combustion temperature. The proton acidic sites from the degraded OMMT layers due to the Hoffman reaction of the modifiers at high temperature played an important role in the catalytic degradation of PP to supply carbon sources that are easy to be catalyzed by nickel catalyst for the growth of MWCNTs. The XRD measurements demonstrated that the nickel compounds were in situ reduced into the Ni(0) state with the aid of hydrogen gas and/or hydrocarbons in the degradation products of PP, and the Ni(O) was really the active site for the growth of MWCNTs. The combination of nickel compounds with OMMT was a key factor to efficiently synthesize MWCNTs via catalytic combustion of PP. (c) 2006 Published by Elsevier Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000244270600031 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61461]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Northeastern Univ, Dept Chem, Shenyang 110004, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Zhiwei,Song, Rongjun,Bi, Wuguo,et al. Polypropylene as a carbon source for the synthesis of multi-walled carbon nanotubes via catalytic combustion[J]. CARBON,2007,45(2):449-458. |
| APA | Jiang, Zhiwei,Song, Rongjun,Bi, Wuguo,Lu, Jun,&Tang, Tao.(2007).Polypropylene as a carbon source for the synthesis of multi-walled carbon nanotubes via catalytic combustion.CARBON,45(2),449-458. |
| MLA | Jiang, Zhiwei,et al."Polypropylene as a carbon source for the synthesis of multi-walled carbon nanotubes via catalytic combustion".CARBON 45.2(2007):449-458. |
入库方式： OAI收割
来源：化学研究所
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