Crystallization behavior of poly(epsilon-caprolactone) in poly(epsilon-caprolactone) and poly(vinyl methyl ether) mixtures
文献类型：期刊论文
| 作者 | Meng, Yanfeng; Li, Hongfei; Huo, Hong; Jiang, Shichun; An, Lijia |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2007-07-15 |
| 卷号 | 105期号:2页码:615-622 |
| 关键词 | Poly(Epsilon-caprolactone) Poly(Vinyl Methyl Ether) Crystallization Mixtures |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.26241 |
| 英文摘要 | The morphological development and crystallization behavior of poly(epsilon-caprolactone) (PCL) in miscible mixtures of PCL and poly(vinyl methyl ether) (PVME) were investigated by optical microscopy as a function of the mixture composition and crystallization temperature. The results indicated that the degree of crystallinity of PCL was independent of the mixture composition upon melt crystallization because the glass-transition temperatures of the mixtures were much lower than the crystallization temperature of PCL. The radii of the PCL spherulites increased linearly with time at crystallization temperatures ranging from 42 to 49 degrees C. The isothermal growth rates of PCL spherulites decreased with the amount of the amorphous PVME components in the mixtures. Accounting for the miscibility of PCL/PVME mixtures, the radial growth rates of PCL spherulites were well described by a kinetic equation involving the Flory-Huggins interaction parameter and the free energy for the nuclei formation in such a way that the theoretical calculations were in good agreement with the experimental data. From the analysis of the equilibrium melting point depression, the interaction energy density of the PVME/PCL system was calculated to be -3.95 J/cm(3). (c) 2007 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000246709500044 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61497]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Shichun |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Ludong Univ, Sch Chem & Mat Sci, Yantai 264025, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Meng, Yanfeng,Li, Hongfei,Huo, Hong,et al. Crystallization behavior of poly(epsilon-caprolactone) in poly(epsilon-caprolactone) and poly(vinyl methyl ether) mixtures[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2007,105(2):615-622. |
| APA | Meng, Yanfeng,Li, Hongfei,Huo, Hong,Jiang, Shichun,&An, Lijia.(2007).Crystallization behavior of poly(epsilon-caprolactone) in poly(epsilon-caprolactone) and poly(vinyl methyl ether) mixtures.JOURNAL OF APPLIED POLYMER SCIENCE,105(2),615-622. |
| MLA | Meng, Yanfeng,et al."Crystallization behavior of poly(epsilon-caprolactone) in poly(epsilon-caprolactone) and poly(vinyl methyl ether) mixtures".JOURNAL OF APPLIED POLYMER SCIENCE 105.2(2007):615-622. |
入库方式： OAI收割
来源：化学研究所
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