Polyaneline nanofibers, prepared by using ferric chloride as both oxidant and dopant
文献类型：期刊论文
| 作者 | Ding Hangjun; Zhu Changjin; Zhou Zhiming; Wan Meixiang |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2007-05-01 |
| 期号 | 5页码:462-466 |
| 关键词 | Polyaniline Nanofibers Ferric Chloride Dopant-free Template-free |
| ISSN号 | 1000-3304 |
| 英文摘要 | Polyaniline (PANI) nanofibers with a higher conductivity (10(-2) similar to 10(-1) S/cm) were synthesized by "template-free" method in the presence of ferric chloride as oxidant at dopant-free via interfacial polymerization of aniline (An). Compared with previous interfacial polymerization, this method is more simple and cheap because ferric chloride acting as both oxidant and dopant at the same time, resulting in omitting external dopant. Moreover, 94 the resulting nanofibers show thinner diameter and higher crystallinity than those of the nanofibers oxidized by APS which perhaps due to its low redox potential of FeCl3. It is also found that the morphology and conductivity of the nanofibers at room-temperature change with the increase of [FeCl3 ]/[An] ratios. The nanofibers were characterized by FTIR and UV-Visible absorption spectra, and the results indicated that they were identical to the emeraldine salt state of PANI. |
| 语种 | 英语 |
| WOS记录号 | WOS:000246990100011 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61505]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ding Hangjun |
| 作者单位 | 1.Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solid Lab,Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding Hangjun,Zhu Changjin,Zhou Zhiming,et al. Polyaneline nanofibers, prepared by using ferric chloride as both oxidant and dopant[J]. ACTA POLYMERICA SINICA,2007(5):462-466. |
| APA | Ding Hangjun,Zhu Changjin,Zhou Zhiming,&Wan Meixiang.(2007).Polyaneline nanofibers, prepared by using ferric chloride as both oxidant and dopant.ACTA POLYMERICA SINICA(5),462-466. |
| MLA | Ding Hangjun,et al."Polyaneline nanofibers, prepared by using ferric chloride as both oxidant and dopant".ACTA POLYMERICA SINICA .5(2007):462-466. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。