Polymer nanocomposite powders and melt spun fibers filled with silica nanoparticles
文献类型:期刊论文
作者 | Rottstegge, J.; Zhang, X.; Zhou, Y.; Xu, D.; Han, C. C.; Wang, D. |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2007-01-05 |
卷号 | 103期号:1页码:218-227 |
关键词 | Fumed Silica Nanocomposites Compatibilization Polypropylene Fibers |
ISSN号 | 0021-8995 |
DOI | 10.1002/app.25162 |
英文摘要 | Nanocomposite powders from polypropylene filled with surface modified and unmodified fumed silica have been prepared from polymer solution to achieve improved mixing and have been forwarded to fiber melt spinning. The surface of the fumed silica was modified with dodecyl alkoxy silanes. Crystallization velocity and viscosity of the PP nanocomposites thereof were determined to ensure good melt spinning processing conditions for all composite compositions. Upon addition of untreated filler particles, a shear thinning and an increased crystallization velocity of the polymer melt was found, while only minor changes were detected in the presence of surface modified fumed silica particles. The composites and the polymer fibers made from these powder composites by melt spinning were mainly characterized by optical microscopy (OM), scanning electron microscopy (SEM), mechanical measurements, differential scanning calorimetry (DSC), and solid-state NMR. The unmodified fumed silica was found to have a strong influence on the mechanical fiber properties, while the surface modified silica only a small one. Fibers were additionally characterized with respect to the uniformity, the PP crystallinity, moisture absorption, and the water contact angle. (C) 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 218-227, 2007 |
语种 | 英语 |
WOS记录号 | WOS:000242060800029 |
出版者 | JOHN WILEY & SONS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/61525] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Rottstegge, J. |
作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Zhongguancun, Peoples R China |
推荐引用方式 GB/T 7714 | Rottstegge, J.,Zhang, X.,Zhou, Y.,et al. Polymer nanocomposite powders and melt spun fibers filled with silica nanoparticles[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2007,103(1):218-227. |
APA | Rottstegge, J.,Zhang, X.,Zhou, Y.,Xu, D.,Han, C. C.,&Wang, D..(2007).Polymer nanocomposite powders and melt spun fibers filled with silica nanoparticles.JOURNAL OF APPLIED POLYMER SCIENCE,103(1),218-227. |
MLA | Rottstegge, J.,et al."Polymer nanocomposite powders and melt spun fibers filled with silica nanoparticles".JOURNAL OF APPLIED POLYMER SCIENCE 103.1(2007):218-227. |
入库方式: OAI收割
来源:化学研究所
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