A novel route to the synthesis of PP-g-PMMA copolymer via ATRP reaction initiated by Si-Cl bond
文献类型：期刊论文
| 作者 | Li, Huayi; Zhao, Haihuan; Zhang, Xiaofan; Lu, Yingying; Hu, Youliang |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2007 |
| 卷号 | 43期号:1页码:109-118 |
| 关键词 | Polypropylene Functionalization Allyldimethylsilane Copolymerization Ziegler-natta Catalyst Coordination Polymerization Atrp Graft Copolymer |
| ISSN号 | 0014-3057 |
| DOI | 10.1016/j.eurolymj.2006.10.010 |
| 英文摘要 | The copolymerization of propylene with allyldimethylsilane (ADMS) was carried out with conventional Ziegler-Natta catalyst supported on MgCl2. The effects of the concentration of ADMS in the feed on the polymerization reaction and copolymer properties were investigated. The resulting copolymer PP-co-ADMS was chlorinated to PP-Si-Cl by refluxing the copolymer with SOCl2 in benzene. The chlorinated copolymer was used to initiate ATRP of MMA with CuCl/PMDETA as catalyst to produce graft copolymer PP-g-PMMA, which was characterized with H-1 NMR, C-13 NMR, GPC and DSC. Polymer blend of iPP/PP-g-PMMA/PMMA was prepared and the results shown that PP-g-PMMA was an effective compatilizer. (c) 2006 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000244019900012 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61535]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Hu, Youliang |
| 作者单位 | Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Huayi,Zhao, Haihuan,Zhang, Xiaofan,et al. A novel route to the synthesis of PP-g-PMMA copolymer via ATRP reaction initiated by Si-Cl bond[J]. EUROPEAN POLYMER JOURNAL,2007,43(1):109-118. |
| APA | Li, Huayi,Zhao, Haihuan,Zhang, Xiaofan,Lu, Yingying,&Hu, Youliang.(2007).A novel route to the synthesis of PP-g-PMMA copolymer via ATRP reaction initiated by Si-Cl bond.EUROPEAN POLYMER JOURNAL,43(1),109-118. |
| MLA | Li, Huayi,et al."A novel route to the synthesis of PP-g-PMMA copolymer via ATRP reaction initiated by Si-Cl bond".EUROPEAN POLYMER JOURNAL 43.1(2007):109-118. |
入库方式： OAI收割
来源：化学研究所
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