Establishing a three-dimensional diagram with solubility parameter representing the general behavior of crystallisation for amorphous poly(ethylene 2,6-naphthalate)
文献类型：期刊论文
| 作者 | Ma, Weiming; Zhai, Wentao; Yu, Jian; He, Jiasong |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2007-10-01 |
| 卷号 | 56期号:10页码:1298-1304 |
| 关键词 | Crystallization Solubility Parameter Supercritical Fluid Poly(Ethylene 2 6-naphthalate) |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.2284 |
| 英文摘要 | Supercritical fluids having different solubility parameters wereobtained by changing the parameters of supercritical C02 and adding a cosolvent (methanol). The crystallization behavior of amorphous poly(ethylene 2,6naphthalate) (PEN) in these supercritical fluids covering a wide range of solubility parameter was investigated using wide-angle X-ray diffraction and differential scanning calorimetry. A three-dimensional diagram of crystallization versus temperature, pressure and solubility parameter (i.e. solvent concentration) was established to represent the general behavior of crystallization for amorphous PEN. Supercritical fluids with a higher overall solubility parameter plasticized the PEN chains more effectively and thus provided moderate conditions to induce the crystallization of amorphous PEN. (c) 2007 Society of Chemical Industry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000249602000018 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61645]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | He, Jiasong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, Key Lab Engn Plast,BNLMS, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Weiming,Zhai, Wentao,Yu, Jian,et al. Establishing a three-dimensional diagram with solubility parameter representing the general behavior of crystallisation for amorphous poly(ethylene 2,6-naphthalate)[J]. POLYMER INTERNATIONAL,2007,56(10):1298-1304. |
| APA | Ma, Weiming,Zhai, Wentao,Yu, Jian,&He, Jiasong.(2007).Establishing a three-dimensional diagram with solubility parameter representing the general behavior of crystallisation for amorphous poly(ethylene 2,6-naphthalate).POLYMER INTERNATIONAL,56(10),1298-1304. |
| MLA | Ma, Weiming,et al."Establishing a three-dimensional diagram with solubility parameter representing the general behavior of crystallisation for amorphous poly(ethylene 2,6-naphthalate)".POLYMER INTERNATIONAL 56.10(2007):1298-1304. |
入库方式： OAI收割
来源：化学研究所
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